2011年8月
Liquid Phase Separation of Polyaromatics on [Cu-2(BDC)(2)(dabco)]
LANGMUIR
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- 巻
- 27
- 号
- 15
- 開始ページ
- 9083
- 終了ページ
- 9087
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/la2018049
- 出版者・発行元
- AMER CHEMICAL SOC
The porous coordination polymer (PCP) [Cu-2(BDC)(2)(dabco)] is capable of selectively adsorbing up to 25 wt % of either 1-methylnaphthalene or 2-methylnaphthalene. Uptakes of unsubstituted naphthalene and 1,4-dimethyl-naphthalene are significantly lower (7-13 wt %), suggesting that monomethyl substituted polyaromatics can be separated from the other fractions. Furthermore, this PCP can perform the difficult separation of 1-methylnaphthalene from 2-methylnaphthalene with separation factors as high as 2.6, proving that specific interactions of the methyl group with the lattice play an important role in determining the adsorption selectivity.
- リンク情報
- ID情報
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- DOI : 10.1021/la2018049
- ISSN : 0743-7463
- Web of Science ID : WOS:000293035300004