2006年5月
Stepwise guest adsorption with large hysteresis in a coordination polymer {[Cu(bhnq)(THF)(2)](THF)}(n) constructed from a flexible hingelike ligand
INORGANIC CHEMISTRY
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- 巻
- 45
- 号
- 11
- 開始ページ
- 4322
- 終了ページ
- 4324
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ic060046e
- 出版者・発行元
- AMER CHEMICAL SOC
Reversible vapochromic behavior of a porous copper(II) coordination polymer {[ Cu(bhnq)(THF)(2)](THF)}(n) ( 1; THF = tetrahydrofuran) constructed from a flexible hingelike ligand H(2)bhnq [2,2'-bis(3-hydroxy- 1,4-naphthoquinone)] has been investigated by adsorption measurements. The isotherms show large hysteretic and stepwise profiles, suggesting the occurrence of the guest-induced framework transformation. The dynamic coil-like behavior of 1 can be controlled through the change of the hydrogen-bonding interactions caused by the reversible and selective incorporation of guest molecules.
- リンク情報
- ID情報
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- DOI : 10.1021/ic060046e
- ISSN : 0020-1669
- Web of Science ID : WOS:000237690700007