2005年
A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone
CHEMICAL COMMUNICATIONS
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- 巻
- 号
- 2
- 開始ページ
- 233
- 終了ページ
- 235
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/b415431b
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(mu(1,1)-N-3)](6) circles in the discrete ferromagnetically-coupled M-II-azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.
- リンク情報
- ID情報
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- DOI : 10.1039/b415431b
- ISSN : 1359-7345
- eISSN : 1364-548X
- Web of Science ID : WOS:000226139700025