論文

査読有り
1996年11月

X-ray investigation on the phase transition in (CH3)(3)NHCl

JOURNAL OF THE KOREAN PHYSICAL SOCIETY
  • M Sugiyama
  • ,
  • M Machida
  • ,
  • N Koyano
  • ,
  • Y Iwata

29
SUPPL. 3
開始ページ
S537
終了ページ
S541
記述言語
英語
掲載種別
研究論文(学術雑誌)
出版者・発行元
KOREAN PHYSICAL SOC

In order to study the phase transition in (CH3)(3)NHCl, the crystal structure of the high temperature phase and the temperature dependence of the lattice parameters were determined by the X-ray diffraction procedures. It is found that the crystal exhibits a monoclinic-to-tetragonal phase transition at 308 K and the space group of the high temperature phase is P4/nmm (Z=2). The !east-squares refinement reveals that the structure is approximately represented by the superposition of the four structures similar to the monoclinic one. The electron density calculated for the three methyl groups shows the four maxima at the positions related by the four fold rotation around the c axis. The result indicates the possibility of the occurrence of the rotational-translational coupling in the tetragonal phase.

リンク情報
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:A1996VW31400038&DestApp=WOS_CPL
ID情報
  • ISSN : 0374-4884
  • Web of Science ID : WOS:A1996VW31400038

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