1999年5月
Crystalline polymer on silica. Geometrical selectivity for azobenzenes through highly-oriented structure
POLYMER
- ,
- ,
- ,
- 巻
- 40
- 号
- 10
- 開始ページ
- 2555
- 終了ページ
- 2560
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/S0032-3861(98)00485-6
- 出版者・発行元
- ELSEVIER SCI LTD
Poly(octadecyl acrylate), ODA(n), with a trimethoxysilyl group at one side of the terminal group was immobilized onto porous silica by using the reactive terminal group. The silica-supported ODA(n) underwent crystalline-to-isotropic phase transition. Interaction between ODA(n) and azobenzenes were evaluated by retention time in the liquid chromatography using the column packed with silica-supported ODA(n). The chromatograph showed complete separation against the geometrical isomers of azobenzenes in methanol-water. The temperature dependence of the separation factor indicated that the selectivity increased with the molecular orientation of ODA(n). Effect of carbonyl-pi interaction due to the acrylate moiety on the selectivity was examined using seven kinds of p-substituted phenylazobenzenes with various Hammett's substituent constants. (C) 1999 Elsevier Science Ltd. All rights reserved.
- リンク情報
- ID情報
-
- DOI : 10.1016/S0032-3861(98)00485-6
- ISSN : 0032-3861
- J-Global ID : 200902130194160014
- Web of Science ID : WOS:000078290700010