論文

査読有り 筆頭著者
2019年6月

Effect of introducing a steam pipe to n-dodecane decomposition by in-liquid plasma for hydrogen production

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Ryoya Shiraishi
  • ,
  • Shinfuku Nomura
  • ,
  • Hiromichi Toyota
  • ,
  • Shinobu Mukasa
  • ,
  • Yuki Amano

44
31
開始ページ
16248
終了ページ
16256
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.ijhydene.2019.04.270
出版者・発行元
PERGAMON-ELSEVIER SCIENCE LTD

A method has been developed to improve the hydrogen production efficiency (HPE) by in-liquid plasma n-dodecane decomposition. A thin steam pipe is placed over the plasma electrode to recover the thermal energy emitted from the plasma to its surroundings. The steam generated by this energy is supplied to the vaporized n-dodecane around the edge of the plasma to cause a steam reforming reaction (SRR). Water pyrolysis is suppressed by not supplying the steam directly to the plasma. A large amount of CO and a small amount of CO2 were detected in the produced gas. This indicates that a strong SRR has occurred. The HPE obtained by this method is 0.28 Nm(3)/kWh, which is two times greater than those obtained by previous methods, and similar to or greater than the yield of water electrolysis. This result is a major advance in the field of plasma heavy hydrocarbon decomposition aimed at hydrogen production. HPE is expected to be further improved by simply increasing the input power, due to synergy between the heat recovery effect of the steam pipe and the bubble stabilization effect. This indicates that this method has a high potential. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.ijhydene.2019.04.270
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000472991100020&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.ijhydene.2019.04.270
  • ISSN : 0360-3199
  • eISSN : 1879-3487
  • Web of Science ID : WOS:000472991100020

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