2011年6月
Crystallinity of Anodic TiO(2) Nanotubes and Bioactivity
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
- ,
- ,
- ,
- ,
- ,
- 巻
- 11
- 号
- 6
- 開始ページ
- 4910
- 終了ページ
- 4918
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1166/jnn.2011.4114
- 出版者・発行元
- AMER SCIENTIFIC PUBLISHERS
Anodic TiO(2) nanotubes were produced on titanium at 20 V using 1 M Na(2)SO(4) and 0.5 wt% NaF. Oxidation for 3 hours produced amorphous tubes of diameter 100 nm and thicknesses 2 mu m. Heat-treatments were done for 3 hours at different temperatures. 300 degrees C treatment converted the amorphous coatings to anatase. 550 and 700 degrees C treatments formed dual anatase and rutile; 850 degrees C treatment crystallized to rutile. The treatment at 700 degrees C produced an oxide surface with higher roughness, lower wetting angle and higher coating adhesion. Bioactivity of the as-oxidized and heated coatings were evaluated by treating them in a simulated body fluid (SBF) to form hydroxyapatite (HA) and the rates of HA formation were compared. Deposits of HA could be seen on the dual oxide structure within 3 days. HA was detected after 7 days in the anatase structure and only after 21 days in the amorphous and rutile structures. In vitro cell culture tests done using mouse osteoblasts indicated that, the 700 degrees C-heated surface showed higher levels of cell activity than the other surfaces. It is concluded that the dual rutile and anatase structure formed by heating the oxide at 700 degrees C is the best of the five surfaces tested.
- リンク情報
- ID情報
-
- DOI : 10.1166/jnn.2011.4114
- ISSN : 1533-4880
- Web of Science ID : WOS:000291568100032