MISC

2002年6月

Preparation and mechanical properties of composite of fibrous cellulose and maleated polyethylene

JOURNAL OF APPLIED POLYMER SCIENCE
  • FR Zhang
  • ,
  • T Endo
  • ,
  • WL Qiu
  • ,
  • LQ Yang
  • ,
  • T Hirotsu

84
11
開始ページ
1971
終了ページ
1980
記述言語
英語
掲載種別
DOI
10.1002/app.10428
出版者・発行元
JOHN WILEY & SONS INC

Fibrous cellulose and maleated polyethylene (FC-MPE) composites were prepared under melt mixing by maleation of polyethylene {PE) to obtain malefic anhydride (MA) grafted PE (MPE) and successive compounding of the resultant MPE with fibrous cellulose (FC). When increasing the content of added MA to 2 wt %, the grafting efficiency of MA decreases gradually to 84% and the grafted MA chains become longer. Scanning electron microscopy (SEM) reveals strong adhesion of MPE to FC in the FC-MPE composite, which is probably due to the increased compatibility between MPE and FC, in contrast to no adhesion of unmaleated PE (UPE) to FC in the FC-UPE composite. This difference in interfacial structure between the FC-MPE and FC-UPE composites results in quite different mechanical properties for them. With an increase in the FC content to 0 wt %, the tensile strength of the FC-MPE composite increases significantly and reaches 125 % that of pure PE. Furthermore, the larger Young's modulus, larger bending elastic modulus, and smaller elongation of the FC-MPE composite strongly indicate effective transfer of the high tensile strength and elasticity of FC to the MPE matrix through the strong adhesion between FC and MPE. (C) 2002 Wiley Periodicals, Inc.

リンク情報
DOI
https://doi.org/10.1002/app.10428
CiNii Articles
http://ci.nii.ac.jp/naid/80015183906
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000174802700002&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/app.10428
  • ISSN : 0021-8995
  • CiNii Articles ID : 80015183906
  • Web of Science ID : WOS:000174802700002

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