2004年1月
X-ray irradiation-induced coloration of manganese in soda-lime silicate glass
JOURNAL OF NON-CRYSTALLINE SOLIDS
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- 巻
- 333
- 号
- 1
- 開始ページ
- 37
- 終了ページ
- 43
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.jnoncrysol.2003.09.040
- 出版者・発行元
- ELSEVIER SCIENCE BV
Coloration of Mn in soda-lime silicate glass by X-ray irradiation was investigated as a coloration method suitable for glass recycling. Mn was initially reduced to Mn2+ With the addition of Fe, Sn or carbon, and the resultant colorless or near-colorless glasses containing no Mn3+ were studied. These glasses turned violet after X-ray irradiation and heat treatment at 200 degreesC due to formation of Mn3+. The color was stable at room temperature and decoloration occurred with heat treatment at 600 degreesC. The addition of Fe or Sn increased the optical absorption by Mn3+ ions. ESR measurement suggests that Mn photo-oxidation occurred through charge transfer from photo-induced hole centers. (C) 2003 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.jnoncrysol.2003.09.040
- ISSN : 0022-3093
- CiNii Articles ID : 80016384607
- Web of Science ID : WOS:000187727200005