1993年
Vapour-phase oxidation of diamond surfaces in O2 studied by diffuse reflectance Fourier-transform infrared and temperture-programmed desorption spectroscopy
Journal of the Chemical Society, Faraday Transactions
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- 巻
- 89
- 号
- 19
- 開始ページ
- 3635
- 終了ページ
- 3640
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1039/FT9938903635
Thermal oxidizing treatments of hydrogenated diamond surfaces have been performed in an O2 environment. Chemisorption of oxygen on diamond surfaces has been investigated by diffuse reflectance Fourier-transform infrared (FTIR), temperature-programmed desorption (TPD), temperature-programmed reaction (TPR) and thermogravimetry (TG). Oxidation of the hydrogenated diamond occurred above 300°C and diamond started to burn out above 480°C in 20% O2. Diffuse reflectance FTIR spectra indicated that the oxidation gave species containing C=O and C-O-C structures on the diamond surface above 300°C. The structures of the chemisorbed species changed with the oxidation temperature. The maximum coverage of oxygen was obtained between 480 and 500°C. TPD spectra of oxidized diamond indicated that the oxygen-containing species were desorbed as CO and CO2 above 480°C. This paper deals with the mechanistic considerations for the oxidation of diamond surfaces.
- リンク情報
- ID情報
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- DOI : 10.1039/FT9938903635
- ISSN : 0956-5000
- identifiers.cinii_nr_id : 9000239248799
- SCOPUS ID : 2142676237