MISC

2000年9月1日

In situ Raman spectroscopy of shock-compressed benzene and its derivatives

Physical Review B - Condensed Matter and Materials Physics
  • T. Kobayashi
  • ,
  • T. Sekine

62
9
開始ページ
5281
終了ページ
5284
記述言語
英語
掲載種別
DOI
10.1103/PhysRevB.62.5281

Real-time Raman spectra of shock compressed benzene and its monosubstitutes, iodobenzene, and nitrobenzene, have been measured in the pressure range up to 7.5 GPa. Spectral peaks show almost linear blueshifts against shock pressure. However, nitrobenzene, compared to the other two compounds, shows smaller shifts. Especially the increase in Raman frequency of the NO2 stretching mode (1346 cm-1) is extremely small. An intermolecular interaction between nitrobenzene molecules seems responsible for this behavior.

リンク情報
DOI
https://doi.org/10.1103/PhysRevB.62.5281
ID情報
  • DOI : 10.1103/PhysRevB.62.5281
  • ISSN : 0163-1829
  • identifiers.cinii_nr_id : 9000239248799
  • SCOPUS ID : 0034261371

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