- ELSEVIER SCI LTD
Flammability limits were measured fora number of multi-fluorinated compounds in a 12 L spherical glass vessel. It was found that the saturated multi-fluorinated compounds with F Substitution rate larger than 0.625 are non-flammable. Those with F substitution rate of 0.625 may or may not be flammable depending on the molecular structure and the humidity condition. A numerical analysis was carried out on the observed values of flammability limits for some 120 compounds including the multi-fluorinated ones. For multi-fluorinated compounds with F substitution rate of 0.6 or less, the flammability limit values can be explained reasonably well by the analysis. It is to be noted, however, that even for the non-flammable multi-fluorinated compounds the numerical analysis tends to predict them to be flammable. (c) 2005 Elsevier Ltd. All rights reserved.
Web of Science ® 被引用回数 : 33
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- DOI : 10.1016/j.firesaf.2005.08.002
- ISSN : 0379-7112
- CiNii Articles ID : 80017679027
- Web of Science ID : WOS:000234821100005