論文

査読有り
2012年3月

Preparation of Nanoporous Ruthenium Catalyst and Its CO Oxidation Characteristics

MATERIALS TRANSACTIONS
  • Masataka Hakamada
  • ,
  • Junichi Motomura
  • ,
  • Fumi Hirashima
  • ,
  • Mamoru Mabuchi

53
3
開始ページ
524
終了ページ
530
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.2320/matertrans.M2011326
出版者・発行元
JAPAN INST METALS

Anodic polarization measurements for various ruthenium (Ru) alloys revealed that hexagonal close-packed nanoporous Ru (np-Ru) can be fabricated by dealloying or selective dissolution of manganese (Mn) from Ru-Mn alloy. The pore size and specific surface area of fabricated np-Ru were 3 nm and 51.5 m(2)g(-1), respectively. An electron diffraction pattern suggested a polycrystalline nature of the fabricated np-Ru, which is perhaps due to the change in the crystal structure during dealloying. The oxidation of carbon monoxide (CO) was efficiently catalyzed by the np-Ru. The activation energy was 82 kJ mol(-1) which is comparable to that of the polycrystalline RuO2/Ru catalyst. The present np-Ru is a novel candidate as a recoverable Ru catalyst. [doi:10.2320/matertrans.M2011326]

リンク情報
DOI
https://doi.org/10.2320/matertrans.M2011326
CiNii Articles
http://ci.nii.ac.jp/naid/10030259615
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000303372400013&DestApp=WOS_CPL
ID情報
  • DOI : 10.2320/matertrans.M2011326
  • ISSN : 1345-9678
  • eISSN : 1347-5320
  • CiNii Articles ID : 10030259615
  • Web of Science ID : WOS:000303372400013

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