2009年4月
Fluorescence switching of photochromic vinylpyrene-substituted 2 '-deoxyguanosine
TETRAHEDRON LETTERS
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- 巻
- 50
- 号
- 13
- 開始ページ
- 1403
- 終了ページ
- 1406
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.tetlet.2009.01.029
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
We synthesized C8-vinylpyrene-substituted 2'-deoxyguanosine (VPy)G and studied the photoregulated reversible E-Z isomerization. When E-isomer was irradiated with visible light (>420 nm), E- to Z-isomerization took place very rapidly, while upon irradiation with UV-Iight (similar to 365 nm), Z-isomer was converted to E-isomer. When Z-isomer was illuminated with 365-400 nm light, no fluorescence was observed, while F-isomer showed a very strong fluorescence emission, indicating that (VPy)G could be a useful fluorescence switching molecule. (C) 2009 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2009.01.029
- ISSN : 0040-4039
- J-Global ID : 200902206336143755
- Web of Science ID : WOS:000264171400010