1998
Facile synthesis of α-fluoroalkyl sulfides under the oxidative desulfurization-fluorination conditions
Bulletin of the Chemical Society of Japan
- ,
- ,
- Volume
- 71
- Number
- 11
- First page
- 2687
- Last page
- 2694
- Language
- English
- Publishing type
- DOI
- 10.1246/bcsj.71.2687
- Publisher
- Chemical Society of Japan
Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5- dimethylhydantoin, various organic sulfides underwent a Pummerer-type rearrangement, followed by fluorination, to give α-fluoro sulfides. The fluoro-Pummerer rearrangement, when applied to RCH(SMe)CF2SMe, gave trifluoro sulfides RCF(SMe)CF2SMe. When an HF-pyridine reagent was used as the fluorinating agent, an oxidative desulfurization-fluorination reaction occurred depending on the structure of the substrates.
- Link information
- ID information
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- DOI : 10.1246/bcsj.71.2687
- ISSN : 0009-2673
- SCOPUS ID : 0031765071