Manabu Kuroboshi

Profile Information

Affiliation: Associate Professor, Graduate School of Natural Science and Technology, Okayama University

Degree: Dr. of Engineering(Kyoto University)
Mr. of Engineering(Kyoto University)

J-GLOBAL ID: 200901028866771146
researchmap Member ID: 1000015723

Research Interests

Research Areas

Nanotechnology/Materials / Synthetic organic chemistry /

Committee Memberships

Awards

Papers

Selective Synthesis of 2,2-Diamino-4,4,6,6-tetrakis(aryloxy)cyclotriphosphazenes N3P3-2,2-(NH2)2-4,4,6,6-(ArO)4

Manabu Kuroboshi, Fumiya Nakamura, Hideo Tanaka

HETEROCYCLES, 106(3) 479-479, 2023
Synthesis of 2-Aryloxy-2,4,4,6,6-pentachlorocyclotriphosphazenes (N3P3Cl5(OAr)): Monoaryloxylatioin of Hexachlorocyclotriphosphazene (N3P3Cl6) and Mass Spectra of Chlorocyclotriphosphazene Derivatives. Difference between EI vs. ESI Methods

Manabu Kuroboshi, Ryota Takahashi, Hideo Tanaka

HETEROCYCLES, 106(4) 695-695, 2023
Synthesis of 2-Anilino-2,4,4,6,6-pentachlorocyclotriphosphazenes (N3P3Cl5(NAr(R)))

Manabu Kuroboshi, Ryota Takahashi, Hideo Tanaka

HETEROCYCLES, 106(6) 1039-1039, 2023
NUCLEOPHILIC SUBSTITUTION OF 2,2-BIS(ARYLTHIO)-4,4,6,6-TETRACHLOROCYCLOTRIPHOSPHAZENE WITH AMMONIA, PHENOXIDE, AND THIOPHENOXIDE

Manabu Kuroboshi, Ayako Ueno, Ayane Kawano, Hideo Tanaka

HETEROCYCLES, 104(1) 69-84, 2022
NEW AND PRACTICAL APPLICATIONS OF FUNCTIONALIZED CYCLOTRIPHOSPHAZENE CORE-BASED MATERIALS

Manabu Kuroboshi, Hideo Tanaka

HETEROCYCLES, 100(10) 1513-1578, Oct, 2020
ELECTROOXIDATION OF CHLORODIPHENYLPHOSPHINE UNDER AMMONIA ATMOSPHERE. SYNTHESIS OF 2,2,4,4,6,6-HEXAPHENYLCYCLOTRIPHOSPHAZENE AND IMINOBIS(AMINODIPHENYLPHOSPHORUS) CHLORIDE

Manabu Kuroboshi, Yasunari Masumoto, Hideo Tanaka

HETEROCYCLES, 98(9) 1258-1264, Sep, 2019
SYNTHESIS OF ARYLTHIOCHLOROCYCLOTRIPHOSPHAZENES

Manabu Kuroboshi, Masaki Mikasa, Hideo Tanaka

HETEROCYCLES, 98(7) 940-953, Jul, 2019
SYNTHESIS OF AMINATED CYCLOTRIPHOSPHAZENES. SOLVENT EFFECTS ON THE PRODUCT-SELECTIVITY OF THE AMINATION

Manabu Kuroboshi, Masahiko Morita, Yasunari Masumoto, Masaki Mikasa, Ryohei Toza, Hideo Tanaka

HETEROCYCLES, 98(7) 931-939, Jul, 2019
Functional monomer impurity affects adhesive performance

Kumiko Yoshihara, Noriyuki Nagaoka, Takumi Okihara, Manabu Kuroboshi, Satoshi Hayakawa, Yukinori Maruo, Goro Nishigawa, Jan De Munck, Yasuhiro Yoshida, Bart Van Meerbeek

DENTAL MATERIALS, 31(12) 1493-1501, Dec, 2015
Reduction of phosphine oxides to the corresponding phosphine derivatives in Mg/Me3SiCl/DMI system

Manabu Kuroboshi, Toshihito Kita, Asuka Aono, Toshimasa Katagiri, Seiya Kikuchi, Syoko Yamane, Hiromu Kawakubo, Hideo Tanaka

TETRAHEDRON LETTERS, 56(7) 918-920, Feb, 2015 Peer-reviewed
DIQUAT DERIVATIVES, A PRECURSOR OF ORGANIC REDUCTANT

Manabu Kuroboshi, Takashi Kondo, Hideo Tanaka

HETEROCYCLES, 90(1) 723-729, Jan, 2015 Peer-reviewed
FACILE SYNTHESIS OF DIETHYL AZODICARBOXYLATE AND DIETHYLHYDRAZODICARBOXYLATE VIA THE SEQUENTIAL BROMINATION AND HOFMANN-TYPE REARRANGEMENT OF ETHYLALLOPHANATE

Hiromu Kawakubo, Tomoko Suzuki, Kazutaka Nishino, Futaba Hara, Tomoyoshi Takano, Yoshito Takebayashi, Masato Onodera, Aya Mitsui, Haruka Yahagi, Hiroyuki Takayama …

SYNTHETIC COMMUNICATIONS, 45(9) 1068-1072, 2015 Peer-reviewed
Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

Manabu Kuroboshi, Tomotake Yano, Shogo Kamenoue, Hiromu Kawakubo, Hideo Tanaka

TETRAHEDRON, 67(32) 5825-5831, Aug, 2011 Peer-reviewed
TMSCl-Promoted Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine

Hideo Tanaka, Tomotake Yano, Kazuma Kobayashi, Syogo Kamenoue, Manabu Kuroboshi, Hiromu Kawakubo

SYNLETT, (4) 582-584, Mar, 2011
Electrooxidative Glycosylation Through C—S Bond Cleavage of 1-Arylthio-2,3-dideoxyglycosides. Synthesis of 2′,3′-Dideoxynucleosides.

Koichi Mitsudo, Takashi Kawaguchi, Seiji Miyahara, Wataru Matsuda, Manabu Kuroboshi, Hideo Tanaka

ChemInform, 37(9), Feb, 2006 Peer-reviewed
TRIS(DIALKYLAMINO)SULFONIUM DIFLUOROTRIMETHYLSILICATE

M KUROBOSHI, T HIYAMA

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 48(11) 1050-1051, Nov, 1990 Peer-reviewed

Misc.

334

SYNTHESIS OF DENDRIMER-TYPE VIOLOGEN AND ITS USE IN Pd-MEDIATED HOMOCOUPLING OF ARYL HALIDES

Manabu Kuroboshi, Atsuki Kojima, Hideo Tanaka

HETEROCYCLES, 94(11) 2132-2140, Nov, 2017
Viologen as catalytic organic reductant: electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

Manabu Kuroboshi, Takuya Shiba, Hideo Tanaka

TETRAHEDRON LETTERS, 54(28) 3666-3668, Jul, 2013
Electroreduction of aryl halides loaded on palladium-immobilized activated carbon

Manabu Kuroboshi, Hiroaki Idei, Naoaki Hara, Yuta Kokui, Hideo Tanaka

Electrochemistry, 81(5) 359-361, May, 2013
Electro-reductive Homo-Coupling Reaction of Aryl Bromides in PdCl2(PPh3)(2)/Pyridinium Salt Double Mediatory Systems

Hideo Tanaka, Manabu Kuroboshi, Ryukei Kataoka, Ryosuke Suzuki

ELECTROCHEMISTRY, 81(5) 356-358, May, 2013
Amphiphilic viologen: Electrochemical generation of organic reductant and pd-catalyzed reductive coupling of aryl halides in water

Manabu Kuroboshi, Takashi Yamamoto, Hideo Tanaka

Synlett, 24(2) 197-200, 2013
Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine in the Presence of Chlorotrimethylsilane

Hiromu Kawakubo, Manabu Kuroboshi, Tomotake Yano, Kazuma Kobayashi, Syogo Kamenoue, Tomomi Akagi, Hideo Tanaka

SYNTHESIS-STUTTGART, (24) 4091-4098, Dec, 2011
A Practical One-Pot Transformation of Triphenylphosphine Oxide to Triphenylphosphine by Reduction of in situ Generated Triphenylphosphine Dichloride

Tomotake Yano, Masakatsu Hoshino, Manabu Kuroboshi, Hideo Tanaka

SYNLETT, (5) 801-803, Mar, 2010
Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine

Tomotake Yano, Manabu Kuroboshi, Hideo Tanaka

TETRAHEDRON LETTERS, 51(4) 698-701, Jan, 2010
Design of Redox-Mediatory Systems for Electro-Organic Synthesis

Hideo Tanaka, Manabu Kuroboshi, Koichi Mitsudo

ELECTROCHEMISTRY, 77(12) 1002-1009, Dec, 2009
Chemo- and Product-selective Electrooxidation of 3-(Arylthiomethyl)-Delta(3)-cephems

Hideo Tanaka, Yoshihisa Tokumaru, Ken-ichi Fukui, Manabu Kuroboshi, Sigeru Torii, Anny Jutand, Christian Amatore

SYNTHESIS-STUTTGART, (20) 3449-3459, Oct, 2009
Electroorganic synthesis in oil-in-water (O/W) nanoemulsion: TEMPO-mediated electrooxidation of amphiphilic alcohols in water

Manabu Kuroboshi, Tomonori Yoshida, Jun Oshitani, Kuniaki Goto, Hideo Tanaka

TETRAHEDRON, 65(34) 7177-7185, Aug, 2009
Electrooxidation of Alcohols in N-Oxyl-Immobilized Silica Gel/Water Disperse System: Approach to Totally Closed System

Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka

SYNTHESIS-STUTTGART, (6) 903-908, Mar, 2009
Development of aqueous media for electro organic synthesis

83(5) 206-214, 2009
Electroreductive Generation of Recyclable Organic Reductant from N,N '-Dioctyl-4,4'-bipyridinium and Pd-Catalyzed Reductive Coupling of Aryl Halides

Manabu Kuroboshi, Ryoto Kobayashi, Takayuki Nakagawa, Hideo Tanaka

SYNLETT, (1) 85-88, Jan, 2009
Recyclable Electron Transfer System: Electroreduction of Viologen in Ionic Liquids and Pd-catalyzed Reductive Coupling of Aryl Halides

Manabu Kuroboshi, Akiko Kuwano, Hideo Tanaka

ELECTROCHEMISTRY, 76(12) 862-864, Dec, 2008
ELECTROOXIDATIVE DESULFURIZATION/CHLORINATION. A FACILE SYNTHESIS OF 4-CHLORO-2-AZETIDINONES, A POTENT INTERMEDIATE FOR CARBAPENEMS

Manabu Kuroboshi, Masayoshi Miyada, Syoichi Tateyama, Hideo Tanaka

HETEROCYCLES, 76(2) 1471-1484, Nov, 2008
Diastereoselective synthesis of 6-bromo-6-(1-hydroxyethyl)penicillanate by cross-coupling of 6,6-dibromopenicillanate and acetaldehyde promoted with grignard reagents: Role of amine ligands

Manabu Kuroboshi, Keiko Mesaki, Syoichi Tateyama, Hideo Tanaka

HETEROCYCLES, 73(1) 877-+, Dec, 2007
Electroorganic synthesis in oil-in-water nanoemulsion: TEMPO-mediated electrooxidation of amphiphilic alcohols in water

Tomonori Yoshida, Manabu Kuroboshi, Jun Oshitani, Kuniaki Gotoh, Hideo Tanaka

SYNLETT, in press(17) 2691-2694, Oct, 2007
Electrooxidative N-halogenation of 2-azetidinone derivatives

Hideo Tanaka, Shin-ya Arai, Yoshinori Ishitobi, Manabu Kuroboshi, Sigeru Torii

ELECTROCHEMISTRY, 74(8) 656-658, Aug, 2006
Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

J Kubota, T Ido, M Kuroboshi, H Tanaka, T Uchida, K Shimamura

TETRAHEDRON, 62(20) 4769-4773, May, 2006

Presentations

125

#1673 Ni-Catalyzed Electroreductive Dehalogenation of Aryl Halides

216th ECS Meeting, 2009
電解塩素化を鍵プロセスとする 4-クロロアゼチジノンの合成

2009年電気化学秋季大会, 2009
水中での電解還元による有機還元剤の調製と炭素－炭素結合形成への応用

2009年電気化学秋季大会, 2009
Ph3P のリサイクルシステムを指向した五価リン化合物の還元反応

第３３回有機電子移動化学討論会, 2009
電解還元を利用する再利用可能な有機還元剤の調製とその利用

第３３回有機電子移動化学討論会, 2009
#618 Electrooxidative Desulfurization/Chlorination. A Facile Synthesis of 4-Chloro-2-azetidinones, A Potent Intermediate for Carbapenems

215th ECS Meeting, 2009
#623 Electroreductive Intramolecular Cyclization of Aryl Halides Using Fluorene Mediators

215th ECS Meeting, 2009
電解塩素化を活用する 4-クロロ-2-アゼチジノンの合成

日本化学会第８９春季年会, 2009
ビオロゲンの電解還元による有機還元剤の発生と反応。アリール／アリールカップリングへの展開

日本化学会第８９春季年会, 2009
活性炭に吸着した芳香族ハロゲン化物の電解還元脱ハロゲン化

日本化学会第８９春季年会, 2009
Al／MXn複合レドックス系を用いるトリフェニルホスフィンオキシドからトリフェニルホスフィンへの One-pot 変換

日本化学会第８９春季年会, 2009
#1512 Recyclable Electron Transfer System: Viologen/Pd-Promoted Reductive Coupling of Aryl Halides in Ionic Liquid

214th ECS Meeting, 2008
水中で機能する有機還元剤の調製と芳香族ハロゲン化物の還元的カップリング反応

第32 回有機電子移動化学討論会, P11, 2008
#535 Pd/Viologen-Promoted Reductive Coupling of Aryl Halides in

213th ECS Meeting, 2008
#562 Electroreductive Dehalogenation/Dimerization of Aryl Halides on an Activated Carbon Adsorbing Layer Using a Stacked-Type Cell

213th ECS Meeting, 2008
活性炭吸着相を反応場とする電解還元脱ハロゲン化

電気化学会７５回大会, 2008
活性炭吸着相を反応場とする芳香族ハロゲン化物の電解還元脱ハロゲン化－積層型セルの開発

日本化学会第８８春季大会, 2008
O/W ナノエマルション系における両親媒性アルコールの電解酸化

日本化学会第８８春季大会, 2008
ビオロゲンを基本骨格とする有機還元剤の循環系の開発

日本化学会第８８春季大会, 2008
還元型ビオロゲンを電子プールとする芳香族ハロゲン化物の水中二量化反応

日本化学会第８８春季大会, 2008

Professional Memberships

Research Projects

シクロトリホスファゼンを核とする無機・有機ハイブリッド多機能化合物の選択的な合成

科学研究費助成事業, 基盤研究(C), 日本学術振興会, Apr, 2020 - Mar, 2023

黒星学
Development of Recyclable Organic Reductants in Aqueous Environment

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (C), Japan Society for the Promotion of Science, 2010 - 2012

KUROBOSHI Manabu
Development and Application of Highly Chemoselective Organic Reductants

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (C), Japan Society for the Promotion of Science, 2007 - 2009

KUROBOSHI Manabu
Electrolysis in solid particles disperse water systems directed toward environmental stress O processes

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Japan Society for the Promotion of Science, 2007 - 2009

TANAKA Hideo, KUROHOSHI Manabu, MITSUDO Koichi
非芳香族化・再芳香族化を戦略とする多置換芳香環の新規構築法の研究

科学研究費助成事業, 奨励研究(A), 日本学術振興会, 1998 - 1999

黒星学
固/液電子伝達系に於ける不斉反応場の構築

科学研究費助成事業, 重点領域研究, 日本学術振興会, 1997 - 1997

田中秀雄, 黒星学
不斉ポリオール系の構築法の開発と天然物合成への展開

科学研究費助成事業, 重点領域研究, 日本学術振興会, 1997 - 1997

鳥居滋, 玄場昭子, 黒星学, 野上潤造
Chemoselective Transformation of C-C Double Bonds by Using Transition-Metal Hediated Electrolysis

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (C), Japan Society for the Promotion of Science, 1996 - 1997

KUROBOSHI Manabu
Generation of Organo Copper Species in Organotin/Coppter (I) Systems and Application to Carbon-Carbon Bond Formation

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Japan Society for the Promotion of Science, 1994 - 1996

TANAKA Hideo, GENBA Akiko, OKUMOTO Hiroshi, KUROBOSHI Manabu
Design of Electron Transfer Catalysts in Electrolysis System

Grants-in-Aid for Scientific Research, Grant-in-Aid for international Scientific Research, Japan Society for the Promotion of Science, 1994 - 1996

TORII Sigeru, KUROBOSHI Manbu, TANAKA Hideo, AMATORE Christian, JUTAND Anny
Design and Synthesis of Novel Elctron-Conductive Materials and Usage as Functionalized Materials for Information

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (A), Japan Society for the Promotion of Science, 1993 - 1996

TORII Sigru, GENBA Akiko, OKUMOTO Hiroshi, INOKUCHI Tsutomu, KUROBOSHI Manabu, TANAKA Hideo
有機パラジウム錯体の新触媒機能の創製

科学研究費助成事業, 重点領域研究, 日本学術振興会, 1995 - 1995

田中秀雄, 黒星学, 鳥居滋
Design, Synthesis, and Evaluation of New Ferroelectric Liquid Crystals

Grants-in-Aid for Scientific Research, Grant-in-Aid for Developmental Scientific Research (B), Japan Society for the Promotion of Science, 1993 - 1995

HIYAMA Tamejiro, TAKEHARA Sadao, KUSUMOTO Tetsuo
「酸化的脱硫フッ素化」によるトリフルオロメチル基置換化合物の簡便合成

科学研究費助成事業, 奨励研究(A), 日本学術振興会, 1993 - 1993

黒星学

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