MISC

2008年10月

Initial stage of fiber structure development in the continuous drawing of poly(ethylene terephthalate)

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
  • Takayoshi Yamaguchi
  • Kyounghou Kim
  • Takahisa Murata
  • Mitsuharu Koide
  • Shuuji Hitoosa
  • Hiroshi Urakawa
  • Yutaka Ohkoshi
  • Yasuo Gotoh
  • Masanobu Nagura
  • Masaru Kotera
  • Kanji Kajiwara
  • 全て表示

46
19
開始ページ
2126
終了ページ
2142
記述言語
英語
掲載種別
DOI
10.1002/polb.21546
出版者・発行元
JOHN WILEY & SONS INC

The initial stage of fiber structure development in the continuous neck-drawing of amorphous poly(ethylene terephthalate) fibers was analyzed by in situ wide-angle X-ray diffraction, small-angle X-ray scattering, and fiber temperature measurements. The time error of the measurements (<600 mu s) was obtained by synchrotron X-ray source and laser irradiation heating. A highly ordered fibrillar-shaped two-dimensional (smectic-like) structure was found to be formed less than 1 ms after necking. By analyzing its (001') and (002') diffractions, the length of the structure 60-70 nm were obtained. A three-dimensionally ordered triclinic crystal began to form with the vanishing of the structure around 1 ms after necking. The amount and size of the crystal were almost saturated within several milliseconds of necking, during which time a mainly exothermic heat of crystallization was also observed. (C) 2008 Wiley Periodicals, Inc.

リンク情報
DOI
https://doi.org/10.1002/polb.21546
CiNii Articles
http://ci.nii.ac.jp/naid/120000823156
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000259589100012&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/polb.21546
  • ISSN : 0887-6266
  • CiNii Articles ID : 120000823156
  • Web of Science ID : WOS:000259589100012

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