2013年10月
Efficient Heterogeneous Catalytic Hydrogenation of Acetone to Isopropanol on Semihollow and Porous Palladium Nanocatalyst
ACS APPLIED MATERIALS & INTERFACES
- ,
- ,
- ,
- ,
- 巻
- 5
- 号
- 19
- 開始ページ
- 9843
- 終了ページ
- 9849
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/am403087m
- 出版者・発行元
- AMER CHEMICAL SOC
Highly efficient and remarkable selective acetone conversion to isopropanol has been achieved via a heterogeneous catalytic hydrogenation of acetone by NaBH4 in the presence of semihollow palladium nanoparticles (PdNPs) grown on ITO substrate. PdNPs with high surface defect grown on an indium tin oxide (ITO) surface were prepared via a simple immersion of the substrate into a solution containing K2PdCl6, sodium dodecyl sulphate (SDS), and formic acid for 2 h at room temperature. The sample showed remarkably high heterogeneous catalytic efficiency by producing 99.8% of isopropanol within 6 min using only 0.28 mu g of PdNPs on the ITO surface. The present system exhibits heterogenenous catalytic hydrogenation efficiency 1 x 10(6) time higher than using the conventional Raney Ni system.
- リンク情報
-
- DOI
- https://doi.org/10.1021/am403087m
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000326356600082&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-84885439357&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0001-7422-9914
- ID情報
-
- DOI : 10.1021/am403087m
- ISSN : 1944-8244
- eISSN : 1944-8252
- ORCIDのPut Code : 13306647
- SCOPUS ID : 84885439357
- Web of Science ID : WOS:000326356600082