2001年7月
Electrochemical analysis of ion-pair formation reactions involving organic dianions using differential pulse voltammetry
ELECTROANALYSIS
- ,
- ,
- 巻
- 13
- 号
- 11
- 開始ページ
- 917
- 終了ページ
- 922
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/1521-4109(200107)13:11<917::AID-ELAN917>3.0.CO;2-D
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Electrode reduction processes involving the metal salts formation of the dianions of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) were observed using the differential pulse voltammetry. A systematic comparison could be performed through the determination of the association constants of the ion pairing equilibria for a series of alkali and alkaline earth metal cations (M+ and M2+) with DDQ(2-) and TCNQ(2-). TCNQ(2-) was found to have no interactions with M+ and be less reactive with M2+ than DDQ(2-), while their formation potentials are almost similar. This difference was discussed in terms of the charge distributions in the dianion states.
- リンク情報
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- DOI
- https://doi.org/10.1002/1521-4109(200107)13:11<917::AID-ELAN917>3.0.CO;2-D
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000170524600005&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-0034877130&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0001-7422-9914
- ID情報
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- DOI : 10.1002/1521-4109(200107)13:11<917::AID-ELAN917>3.0.CO;2-D
- ISSN : 1040-0397
- ORCIDのPut Code : 13306800
- SCOPUS ID : 0034877130
- Web of Science ID : WOS:000170524600005