論文

査読有り
2015年5月

Electrochemical Investigation of Metal Oxide Conducting Electrodes for Direct Detection of Sulfide

ELECTROANALYSIS
  • Md Abdul Aziz
  • ,
  • Manzar Sohail
  • ,
  • Munetaka Oyama
  • ,
  • Wael Mahfoz

27
5
開始ページ
1268
終了ページ
1275
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/elan.201400539
出版者・発行元
WILEY-V C H VERLAG GMBH

This study examined the performance of four conducting metal oxide electrodes for the direct electrochemical analysis of sulfide; the electrode materials studied were indium tin oxide (ITO), fluorine doped tin oxide (FTO), aluminum doped zinc oxide (AZO) and gallium doped zinc oxide (GZO). Cyclic voltammetry (CV) results obtained using the ITO, AZO, GZO and FTO electrodes showed direct electrooxidation peak potential of sulfide at 381, 507, 400, and 850 mV vs. Ag/AgCl, respectively; however, the less positive oxidation potential and high catalytic current response of the ITO electrode made it the electrode of choice for the direct oxidation of sulfide. The effects of different electrolytes and buffer solutions on the CV responses were also evaluated. A linear concentration range up to 350 mu M and a detection limit of 8.0 mu M were achieved. CV response was highly reproducible, remaining unaffected even after 50 measurements. The sensor was found to have good selectivity, with no interference from sulfite, sulfate or chloride ions. The present findings demonstrate that the bare ITO electrode can be used as the basis of an inexpensive, sensitive, selective and robust sulfide sensor.

リンク情報
DOI
https://doi.org/10.1002/elan.201400539
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000356605100026&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84929133593&partnerID=MN8TOARS
URL
http://orcid.org/0000-0001-7422-9914
ID情報
  • DOI : 10.1002/elan.201400539
  • ISSN : 1040-0397
  • eISSN : 1521-4109
  • ORCIDのPut Code : 16647568
  • SCOPUS ID : 84929133593
  • Web of Science ID : WOS:000356605100026

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