論文

査読有り
2005年3月

Thermal expansion and contraction of polymer thin films

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
  • T Kanaya
  • ,
  • T Miyazaki
  • ,
  • R Inoue
  • ,
  • K Nishida

242
3
開始ページ
595
終了ページ
606
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/pssb.200460378
出版者・発行元
WILEY-V C H VERLAG GMBH

We have studied thermal expansion and contraction of polystyrene thin film supported on silicon substrate using X-ray reflectivity and inelastic neutron scattering techniques. In annealing experiments, we found fast and very slow contraction processes in the thin films above the glass transition temperature. The fast one was attributed to normal relaxation (annealing) process observed in bulk and responsible partly for the reported apparent negative expansivity. In addition, we found extremely slow re-expansion process in the glassy state. The ultra-slow contraction and re-expansion have been assigned to the lateral expansion and contraction of the film, respectively. Using well-annealed films, we have evaluated thermal expansivity as a function of film thickness, and found that it decreases with film thickness in a thickness range below twice of radius of gyration of a polymer chain 2R(g), in the glassy state. The decrease has been attributed to hardening of harmonic force constant due to confinement in a thin film. This idea was confirmed in the inelastic neutron scattering measurements. (c) 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

リンク情報
DOI
https://doi.org/10.1002/pssb.200460378
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000228020100018&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/pssb.200460378
  • ISSN : 0370-1972
  • Web of Science ID : WOS:000228020100018

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