論文

査読有り
2007年2月

X-ray reflectivity studies on glass transition of free standing polystyrene thin films

EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS
  • T. Miyazaki
  • ,
  • R. Inoue
  • ,
  • K. Nishida
  • ,
  • T. Kanaya

141
開始ページ
203
終了ページ
206
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1140/epjst/e2007-00041-y
出版者・発行元
SPRINGER HEIDELBERG

We have studied thermal expansion of free standing polystyrene thin films using X-ray reflectivity to elucidate the glass transition temperature and the thermal expansivity. We found that the glass transition temperature T(g) decreased with the film thickness, depending on molecular weight. The reduction in the free standing films is much larger than in the supported films on Si substrate, suggesting that some segmental motions are activated due to free surfaces on both sides in the free standing films. We also found that the thermal expansivity in the glass and the melt decreased with the film thickness. This decrease must be attributable to chain confinement effects.

リンク情報
DOI
https://doi.org/10.1140/epjst/e2007-00041-y
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000245472000035&DestApp=WOS_CPL
ID情報
  • DOI : 10.1140/epjst/e2007-00041-y
  • ISSN : 1951-6355
  • Web of Science ID : WOS:000245472000035

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