論文

査読有り
2011年2月

Distributions of glass-transition temperature and thermal expansivity in multilayered polystyrene thin films studied by neutron reflectivity

PHYSICAL REVIEW E
  • Rintaro Inoue
  • ,
  • Kazuko Kawashima
  • ,
  • Kazuya Matsui
  • ,
  • Toshiji Kanaya
  • ,
  • Koji Nishida
  • ,
  • Go Matsuba
  • ,
  • Masahiro Hino

83
2
開始ページ
1
終了ページ
21801
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevE.83.021801
出版者・発行元
AMER PHYSICAL SOC

We performed neutron reflectivity measurements on multilayered polymer thin films consisting of alternatively stacked deuterated polystyrene (d-PS) and hydrogenated polystyrene (h-PS) layers similar to 200 angstrom thick as a function of temperature covering the glass-transition temperature T(g), and we found a wide distribution of T(g) as well as a distribution of the thermal expansivity a within the thin films, implying the dynamic heterogeneity of the thin films along the depth direction. The reported anomalous film thickness dependences of T(g) and alpha were reasonably understood in terms of the distributions, showing that the surface mobile layer and the bottom hard interfacial layer are, respectively, responsible for the depressions of T(g) and alpha with decreasing film thickness. The molecular mobility in each layer is also discussed in relation to the distribution of T(g), based on the results on mutual diffusion at the layer interface.

リンク情報
DOI
https://doi.org/10.1103/PhysRevE.83.021801
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201102286028916435
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000287078700003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevE.83.021801
  • ISSN : 1539-3755
  • J-Global ID : 201102286028916435
  • Web of Science ID : WOS:000287078700003

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