2006年2月
Infrared-to-visible upconversion of rare-earth doped glass ceramics containing CaF2 crystals
J.Alloys and Compounds
- ,
- 巻
- 408
- 号
- 開始ページ
- 842
- 終了ページ
- 844
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.jallcom.2005.01.096
- 出版者・発行元
- ELSEVIER SCIENCE SA
Oxy-fluoride glass ceramics containing CaF2, crystals doped with YbF3-LnF(3) (Ln = Er, Tm) were prepared by heat-treatment from SiO2-Al2O3-CaO-CaF2 glasses. The upconversion emission spectra of Er3+ and Tm3+ ions in the visible range were measured by 970 nm pumping. In the spectrum of the Er doped sample, 540 nm upconversion band due to the S-4(3/2)-I-4(15/2) and 660 nm band due to the F-4(9/2)-I-4(15/2) were observed. In the Tm doped sample, a blue upconversion emission band due to the (1)G(4)-H-3(6) was observed at 480 nm as well as an 800 nm band. The intensity of these upconversion emissions were very weak in the corresponding as-made glasses. These results indicate that rare-earth ions are incorporated in the CaF2 crystal phases after crystallization and the energy transfer efficiency from Yb3+ to Er3+ or Tm3+ are dramatically improved. (c) 2005 Elsevier B.V. All rights reserved.
- リンク情報
-
- DOI
- https://doi.org/10.1016/j.jallcom.2005.01.096
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000235445300192&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-31144470301&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0002-7620-0119
- ID情報
-
- DOI : 10.1016/j.jallcom.2005.01.096
- ISSN : 0925-8388
- ORCIDのPut Code : 34071562
- SCOPUS ID : 31144470301
- Web of Science ID : WOS:000235445300192