2017年8月
Electrochemical lithium intercalation behavior of pristine and milled hexagonal boron nitride
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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- 巻
- 799
- 号
- 開始ページ
- 263
- 終了ページ
- 269
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jelechem.2017.06.017
- 出版者・発行元
- ELSEVIER SCIENCE SA
Hexagonal boron nitride (h-BN) has been explored for lithium intercalation due to its similar crystal structure to graphite, a well-known anode material for Li-ion secondary batteries. Lithium h-BN intercalation compounds (Li-BNICs) have been successfully synthesized through heat treatment. In this study, potential physical properties related to electrical conductivity were investigated using pristine and milled h-BN, which is further mixed/combined with milled graphite. The electrochemical properties were characterized by cyclic voltammetry (CV) and galvanostatic cycling with potential limitation (GCPL). The chemical potential of h-BN was estimated about 1.0 V versus Li/Li+ and a two-phase reaction was suggested. Accordingly, Li-BNIC is more stable than Li-GICs (lithium graphite intercalation compounds) in terms of thermal stability.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.jelechem.2017.06.017
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000411847300033&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85020816892&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-4841-7932
- ID情報
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- DOI : 10.1016/j.jelechem.2017.06.017
- ISSN : 1572-6657
- eISSN : 1873-2569
- ORCIDのPut Code : 48184879
- SCOPUS ID : 85020816892
- Web of Science ID : WOS:000411847300033