In this study, Fe-X at% Si alloy (X=70.5, 80.0 and 96.0), Re-64.3 at% Si and Mo-66.7 at% Si disk specimens were prepared by spark plasma sintering, and their friction and wear properties were investigated when they were slid against Si3N4 ball specimens in ethyl alcohol. The friction and wear properties of Si ingots were also examined. Fe-70.5 at% Si, Fe-80.0 at% Si, Fe-96.0 at% Si and Re-64.3 at% Si disk specimens exhibited friction coefficients as low as 0.15. It is considered that the low friction of the Fe-70.5 at% Si, Fe-80.5 at% Si and Fe-96.0 at% Si disk specimens was due to the formation of low friction silicon alkoxide and polyoxysilane on the worn surfaces of the disk specimens and the paired ball specimens. Re-64.3 at% Si disk specimens exhibited the highest microvickers hardness of all the disk specimens prepared in this study. In addition, the microvickers hardness of the Fe-X at% Si (X=70.5, 80.0, 96.0 and 100) disk specimen increased with increasing the Si content. Moreover, it was difficult to obtain dense Fe-90.0 at% Si disk specimens by sintering the annealed and crushed Fe-90.0 at% Si powder. However, dense Fe-96.0 at% Si disk specimens could be obtained by sintering the Fe-90.0 at% Si powder at 1403 K. (C) 2013 Elsevier Ltd. All rights reserved.