2011年11月24日
π back-bonding of iron(II) complexes supported by tris(pyrid-2-ylmethyl) amine and its nitro-substituted derivatives
Journal of Physical Chemistry A
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- 巻
- 115
- 号
- 46
- 開始ページ
- 13589
- 終了ページ
- 13595
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jp2069539
- 出版者・発行元
- AMER CHEMICAL SOC
The electronic and geometric structures of a series of iron(II) complexes supported by tetradentate tris(pyrid-2-ylmethyl)amine-type ligands with different numbers of 4-nitropyridine groups, [(PyCH 2) 3 - n(4-NO 2PyCH 2) nN] (n ≥ 0 - 3), were examined by X-ray absorption fine-structure and variable-temperature 1H NMR spectroscopies and theoretical calculations to reveal how the low-spin state is stabilized through π back-bonding interactions between iron(II) and 4-nitropyridine donor group(s). © 2011 American Chemical Society.
- リンク情報
- ID情報
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- DOI : 10.1021/jp2069539
- ISSN : 1089-5639
- ISSN : 1520-5215
- eISSN : 1520-5215
- PubMed ID : 21992441
- SCOPUS ID : 81555201640