2004年3月
A simple synthesis of 6-deoxoteasterone and its 20-epimer
TETRAHEDRON LETTERS
- ,
- ,
- ,
- ,
- 巻
- 45
- 号
- 13
- 開始ページ
- 2767
- 終了ページ
- 2769
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.tetlet.2004.02.033
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
6-Deoxoteasterone, a brassinolide biosynthetic intermediate, and its 20-epimer were synthesized from steroidal 17-olefin and chiral alpha-alkoxyaldehycle using a Lewis acid mediated carbonyl-ene reaction its the key step. In this reaction, unusual stereo-selectivity was observed. (C) 2004 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2004.02.033
- ISSN : 0040-4039
- J-Global ID : 200902272328212481
- Web of Science ID : WOS:000220324300013