1985年
Metabolism of a Non-phenolic β-O-4 Lignin Substructure Model Compound by Coriolus versicolor
Agricultural and Biological Chemistry
- ,
- ,
- 巻
- 49
- 号
- 8
- 開始ページ
- 2325
- 終了ページ
- 2330
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1271/bbb1961.49.2325
A non-phenolic β-O-4 lignin substructure model, 4-ethoxy-3-methoxyphenylglycerol-β-syringaldehyde ether (I), was metabolized by a ligninolytic culture of Coriolus versicolor. Based on the identification of the metabolic products (II~XI), the following reactions were found to occur in the culture
a) oxidation (III) and reduction (II) at the benzyl (Ca') position of the substrate (I), b) β-ether cleavage to give arylglycerols (IV, V), and c) Cα-Cβ cleavage of the arylglycerols and/or arylglycerol moiety of the substrate (I). In addition, β-deoxy diol (VI) and y-formylglycerol (VII) were obtained as degradation products from substrate (I). © 1985, Japan Society for Bioscience, Biotechnology, and Agrochemistry. All rights reserved.
a) oxidation (III) and reduction (II) at the benzyl (Ca') position of the substrate (I), b) β-ether cleavage to give arylglycerols (IV, V), and c) Cα-Cβ cleavage of the arylglycerols and/or arylglycerol moiety of the substrate (I). In addition, β-deoxy diol (VI) and y-formylglycerol (VII) were obtained as degradation products from substrate (I). © 1985, Japan Society for Bioscience, Biotechnology, and Agrochemistry. All rights reserved.
- ID情報
-
- DOI : 10.1271/bbb1961.49.2325
- ISSN : 0002-1369
- SCOPUS ID : 85004503652