1997年11月
Rovibrational states of a tetrahedral molecule in a hexagonal close-packed crystal
JOURNAL OF CHEMICAL PHYSICS
- 巻
- 107
- 号
- 19
- 開始ページ
- 7695
- 終了ページ
- 7706
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1063/1.475084
- 出版者・発行元
- AMER INST PHYSICS
The vibration-rotation states of a tetrahedral molecule in a field of D-3h symmetry are studied by an extended group theory. Symmetry adapted rotational wave functions for the ground and the triply degenerate excited vibrational states are constructed. The crystal field potential is derived explicitly for a tetrahedral molecule in a hexagonal close-packed crystal. As an example, the rovibrational energy states of methane in solid parahydrogen are computed. Optical selection rules are also derived from the theory. (C) 1997 American Institute of Physics.
- リンク情報
- ID情報
-
- DOI : 10.1063/1.475084
- ISSN : 0021-9606
- CiNii Articles ID : 30015645497
- Web of Science ID : WOS:A1997YG65500013