2009年
Preparation and Characterization of Inclusion Compounds Using TEMPOL and an Organic 1-D Nanochannel as a Template
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
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- 巻
- 506
- 号
- 開始ページ
- 150
- 終了ページ
- 167
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1080/15421400902987545
- 出版者・発行元
- TAYLOR & FRANCIS LTD
Inclusion of 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPOL) radical into an organic one-dimensional (1-D) nanochannels formed in guest-free tris(o-phenylenedioxy)cyclotriphosphazene (TPP) was attempted. The inclusion of TEMPOL molecules adsorbed into the TPP nanochannel and their molecular orientation and dynamics were confirmed by temperature-dependent election spin resonance (ESR) measurements. In the specimens prepared by co-precipitation, the existence of 1-D spin diffusion was suggested from the ESR line shape, but the diffusion was not as effective as in the case of the TPP and 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) inclusion compound reported in our previous article. These results imply a new methodology for the preparation of a new organic magnet using TPP as a template.
- リンク情報
- ID情報
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- DOI : 10.1080/15421400902987545
- ISSN : 1542-1406
- Web of Science ID : WOS:000268720400012