2011年2月
Cupric Superoxo-Mediated Intermolecular C-H Activation Chemistry
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- 巻
- 133
- 号
- 6
- 開始ページ
- 1702
- 終了ページ
- 1705
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/ja110466q
- 出版者・発行元
- AMER CHEMICAL SOC
The new cupric superoxo complex [LCu(II)(O(2)(center dot-))](+), which possesses particularly strong O-O and Cu-O bonding, is capable of intermolecular C-H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with a deuterium kinetic isotope effect (KIE) of 12.1, similar to that observed for certain copper monooxygenases.
- リンク情報
- ID情報
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- DOI : 10.1021/ja110466q
- ISSN : 0002-7863
- Web of Science ID : WOS:000287831800024