論文

査読有り
2009年12月

Preparation of alpha,beta-Unsaturated Lactams through Intramolecular Electrophilic Carbamoylation of Alkenes

SYNTHESIS-STUTTGART
  • Yoshizumi Yasui
  • ,
  • Issei Kakinokihara
  • ,
  • Hiroshi Takeda
  • ,
  • Yoshiji Takemoto

23
開始ページ
3989
終了ページ
3993
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1055/s-0029-1217028
出版者・発行元
GEORG THIEME VERLAG KG

A general synthetic method for the preparation of alpha,beta-unsaturated lactams starting from alkenylchloroformamides has been developed. The reaction was complete within five minutes at 150 degrees C in N-methylpyrrolidone with a catalytic amount of HBr under microwave irradiation. Not only six-membered lactams, but also five- and seven-membered lactams were obtained in high yields.

リンク情報
DOI
https://doi.org/10.1055/s-0029-1217028
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000272974400009&DestApp=WOS_CPL
ID情報
  • DOI : 10.1055/s-0029-1217028
  • ISSN : 0039-7881
  • Web of Science ID : WOS:000272974400009

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