2018年1月4日
Chemical Stimulus-responsive Folding and Unfolding of a Dendrimeric Assembly
Chemistry - An Asian Journal
- ,
- ,
- ,
- 巻
- 13
- 号
- 1
- 開始ページ
- 35
- 終了ページ
- 40
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/asia.201701487
- 出版者・発行元
- John Wiley and Sons Ltd
A dendrimeric trimer undergoes folding and unfolding in response to a chemical stimulus. The trimer of interest contains a central dendrimer with a butadiyne-linked zinc porphyrin dimer ((ZnP)2) core, in addition to two terminal dendrimers with zinc porphyrin (ZnP) cores. The obtained absorption spectra indicate that the unfolded form is the exclusive conformer in chloroform, while the addition of 1,4-diazabicyclo[2.2.2]octane (DABCO) in chloroform leads to transformation from the unfolded to the folded structure containing two DABCO units per trimer
the folded structure originates from the cross-linking of (ZnP)2 and ZnP with DABCO. Moreover, the addition of excess DABCO promotes the generation of the unfolded structure containing four DABCO units.
the folded structure originates from the cross-linking of (ZnP)2 and ZnP with DABCO. Moreover, the addition of excess DABCO promotes the generation of the unfolded structure containing four DABCO units.
- ID情報
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- DOI : 10.1002/asia.201701487
- ISSN : 1861-471X
- ISSN : 1861-4728
- SCOPUS ID : 85037348936