MASHIMA Kazushi

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Name
MASHIMA Kazushi
Affiliation
Osaka University
Section
Graduate School of Engineering Science Department of Materials Engineering Science
Job title
Professor
Degree
Ph.D.(Osaka University), Master(Osaka University)
Research funding number
70159143
ORCID ID
0000-0002-1316-2995

Research Areas

 
 

Academic & Professional Experience

 
1982
 - 
1988
Institute for Molecular Science
 
1988
 - 
1991
Kyoto Univ.
 
1991
 - 
1993
Osaka Univ.
 
1993
   
 
-
 

Education

 
 
 - 
1981
Macromolecular Science, Graduate School of Science, Osaka University
 
 
 - 
1983
Macromolecular Science, Graduate School of Science, Osaka University
 
 
 - 
1979
Macromolecular Science, Faculty of Science, Osaka University
 

Awards & Honors

 
Mar 2019
Humbldt Reaserch Award, Alexander von Humboldt Foundation
 
Aug 2000
Substituent Effect on Organotin Tp* Compounds as the Tp* Reagent for the Preparation of Mono Tp* Complexes of Group 4—6 Metals (Tp* = Hydrotris(3,5-dimethylpyrazolyl)borate), BCSJ Best Paper Award
 

Published Papers

 
Bernard F. Parker, Hiromu Hosoya, John Arnold, Hayato Tsurugi, Kazushi Mashima
Inorganic Chemistry      Sep 2019   [Refereed]
Hayato Tsurugi, Yuri Ikeda, Koichi Shinohara, Satoru Shirase, Nozomi Toya, Shinji Tanaka, Kazushi Mashima
Inorganic Chemistry      Sep 2019   [Refereed]
Kento Kawakita, Yuya Kakiuchi, Evan P. Beaumier, Ian A. Tonks, Hayato Tsurugi, Kazushi Mashima
Inorganic Chemistry      Sep 2019   [Refereed]
Fabian Brüning, Haruki Nagae, Daniel Käch, Kazushi Mashima, Antonio Togni
Chemistry – A European Journal   25(46) 10818   Aug 2019   [Refereed]
Kento Kawakita, Evan P. Beaumier, Yuya Kakiuchi, Hayato Tsurugi, Ian A. Tonks, Kazushi Mashima
Journal of the American Chemical Society   141(10) 4194   Mar 2019   [Refereed]
Hayato Tsurugi, Kazushi Mashima
Accounts of Chemical Research   52(3) 769   Mar 2019   [Refereed]
Payel Laskar, Keishi Yamamoto, Kohei Nishi, Hideaki Ikeda, Hayato Tsurugi, Kazushi Mashima
Organometallics   38(3) 722   Feb 2019   [Refereed]
Hayato Tsurugi, Kazushi Mashima
Chemistry - A European Journal   25(4) 913   Jan 2019   [Refereed]
Yohei Ueda, Nagataka Tsujimoto, Taiga Yurino, Hayato Tsurugi, Kazushi Mashima
Chemical Science   10(4) 994   2019   [Refereed]
Haruka Nishiyama, Hiromu Hosoya, Bernard F. Parker, John Arnold, Hayato Tsurugi, Kazushi Mashima
Chemical Communications   55(50) 7247   2019   [Refereed]
Haruki Nagae, Takahiro Hirai, Daiki Kato, Shusei Soma, Shin-ya Akebi, Kazushi Mashima
Chemical Science   10(10) 2860   2019   [Refereed]
Zachary W. Davis-Gilbert, Kento Kawakita, Daniel R. Blechschmidt, Hayato Tsurugi, Kazushi Mashima, Ian A. Tonks
Organometallics   37(23) 4439   Dec 2018   [Refereed]
Satoru Shirase, Koichi Shinohara, Hayato Tsurugi, Kazushi Mashima
ACS Catalysis   8(8) 6939   Aug 2018   [Refereed]
Argha Bhattacharjee, Hiromu Hosoya, Hideaki Ikeda, Kohei Nishi, Hayato Tsurugi, Kazushi Mashima
Chemistry - A European Journal   24(44) 11278   Aug 2018   [Refereed]
Haruki Nagae, Abhinanda Kundu, Mariko Inoue, Hayato Tsurugi, Kazushi Mashima
Asian Journal of Organic Chemistry   7(7) 1256   Jul 2018   [Refereed]
Mao Noguchi, Katsunori Suzuki, Jun Kobayashi, Taiga Yurino, Hayato Tsurugi, Kazushi Mashima, Makoto Yamashita
Organometallics   37(12) 1833   Jun 2018   [Refereed]
Pramanik S, Rej S, Kando S, Tsurugi H, Mashima K.
Journal of Organic Chemistry   83(4) 2409-2417   2018   [Refereed]
Rej S, Tsurugi H, Mashima K.
Coordination Chemistry Reviews   355 223-239   2018   [Refereed]
Ikeda H, Nishi K, Tsurugi H, Mashima K.
Chemical Communications   54(30) 3709-3711   2018   [Refereed]
Nagae H, Aoki R, Akutagawa S, Kleemann J, Tagawa R, Schindler T, Choi G, Spaniol T. P, Tsurugi H, Okuda J, Mashima K.
Angewandte Chemie-International Edition   57(9) 2492-2496   2018   [Refereed]
Morisaki K, Morimoto H, Mashima K, Ohshima T.
Journal of Synthetic Organic Chemistry Japan   76(3) 226-240   2018   [Refereed]
Tobias Schindler, Albert Paparo, Haruka Nishiyama, Thomas P. Spaniol, Hayato Tsurugi, Kazushi Mashima, Jun Okuda
Dalton Transactions   47(38) 13328   2018   [Refereed]
Nishii Y, Hirai T, Fernandez S, Knochel P, Mashima K.
European Journal of Organic Chemistry   (34) 5010-5014   2017   [Refereed]
Higuchi T, Tagawa R, Iimuro A, Akiyama S, Nagae H, Mashima K.
Chemistry-a European Journal   23(52) 12795-12804   2017   [Refereed]
Laskar P, Yamamoto K, Srinivas A, Mifleur A, Nagae H, Tsurugi H, Mashima K.
Dalton Transactions   46(38) 13043-13054   2017   [Refereed]
Nishiyama H, Ikeda H, Saito T, Kriegel B, Tsurugi H, Arnold J, Mashima K.
Journal of the American Chemical Society   139(18) 6494-6505   2017   [Refereed]
Nagae H, Kundu A, Tsurugi H, Mashima K.
Organometallics   36(16) 3061-3067   2017   [Refereed]
Rej S, Majumdar M, Kando S, Sugino Y, Tsurugi H, Mashima K.
Inorganic Chemistry   56(1) 634-644   2017   [Refereed]
Majhi P. K, Ikeda H, Sasamori T, Tsurugi H, Mashima K, Tokitoh N.
Organometallics   36(7) 1224-1226   2017   [Refereed]
Mukherjee D, Shirase S, Beckerle K, Spaniol T. P, Mashima K, Okuda J.
Dalton Transactions   46(26) 8451-8457   2017   [Refereed]
Nishii Y, Hirai T, Fernandez S, Knochel P, Mashima K.
European Journal of Organic Chemistry   (34) 4995   2017   [Refereed]
Morisaki K, Morimoto H, Mashima K, Ohshima T.
Heterocycles   95(2) 637-661   2017   [Refereed]
Rej S, Pramanik S, Tsurugi H, Mashima K.
Chemical Communications   53(98) 13157-13160   2017   [Refereed]
Higashihara K, Higashida K, Nagae H, Mashima K.
Abstracts of Papers of the American Chemical Society   253    2017   [Refereed]
Mashima K, Nagae H, Aoki R, Spaniol T, Okuda J.
Abstracts of Papers of the American Chemical Society   253    2017   [Refereed]
Shirase S, Tsurugi H, Mashima K.
Abstracts of Papers of the American Chemical Society   253    2017   [Refereed]
Iimuro A, Higashida K, Nagae H, Mashima K.
Heterocycles   95(1) 63-80   2017   [Refereed]
Nagae H, Hato W, Kawakita K, Tsurugi H, Mashima K.
Chemistry-a European Journal   23(3) 586-596   2017   [Refereed]
Tanahashi H, Ikeda H, Tsurugi H, Mashima K.
Inorganic Chemistry   55(4) 1446-1452   2016   [Refereed]
Yamamoto K, Higashida K, Nagae H, Tsurugi H, Mashima K.
Helvetica Chimica Acta   99(11) 848-858   2016   [Refereed]
Agura K, Hayashi Y, Wada M, Nakatake D, Mashima K, Ohshima T.
Chemistry-an Asian Journal   11(10) 1548-1554   2016   [Refereed]
Nishiyama H, Yamamoto K, Sauer A, Ikeda H, Spaniol T. P, Tsurugi H, Mashima K, Okuda J.
Organometallics   35(7) 932-935   2016   [Refereed]
Morisaki K, Sawa M, Yonesaki R, Morimoto H, Mashima K, Ohshima T.
Journal of the American Chemical Society   138(19) 6194-6203   2016   [Refereed]
Mukherjee D, Shirase S, Spaniol T. P, Mashima K, Okuda J.
Chemical Communications   52(89) 13155-13158   2016   [Refereed]
Mougel V, Chan K. W, Siddiqi G, Kawakita K, Nagae H, Tsurugi H, Mashima K, Safonova O, Coperet C.
Acs Central Science   2(8) 569-576   2016   [Refereed]
Higashida K, Nagae H, Mashima K.
Advanced Synthesis & Catalysis   358(24) 3949-3954   2016   [Refereed]
Lopez M, Kondo A, Yamamoto K, Tsurugi H, Mashima K.
Abstracts of Papers of the American Chemical Society   251    2016   [Refereed]

Misc

 
長江春樹, 劒隼人, 真島和志
化学   74(8) 66‐67   Aug 2019
Development of Activation Process of Heterogeneous Olefin Metathesis Catalysts Using Organosilicon Reducing Agents and Characterization of Catalytically Active Species
MASHIMA Kazushi
Manufacturing & technology   69(2) 53-58   2017
Preparation, Characterization and Thermal Reactions of 1-oxa-2-Zirconacyclopentanes and 1-Oxa-2-Zirconacyclohexane.
J. Chem. Soc. , Dalton Trans.      1991
Synthesis and Characterization of Mono-and Tri-mulear Ruthenium Complexes of 2, 2-Bis (diphenylphosphino)-1, 1'-binaphthyl and Their Catalytic Activity.
J. Chem. Soc. , Dalton Trans.      1992
16 Electron Haef-sandwich Ru(II)-Thiolate Complexes, Ru(SAr)2 (n6-p-cymere) (Ar=2, 6-dimethyl phenyl ; 2, 4, 6-triisoprop ylphenyl).
Chem. Lett      1992
Preparation and Crystal Characterization of Cationic Dinuclear Ru(II)-Thiolate Comple, [Ru2(SPL)36-p-cymene)2]Y(Y2cl and PF6)
Chem. Lett      1992
Bull. Chem. Soc. Jpn   64(8) 2475-2483   1991
Synthesis and Reaction of Bis(allyl)tantalum(III) Complexes ; Crystal Structure of Ta(η5-C5Me)(η3-phenylallyl)2
J. Organomet. Chem.   455(1) C6-C8   1993
Monocyclooctatetraenyl-thiosamarium Complexes Derived from the Reaction of Metalic Samarium with Cyclooctateraene and Diaryl Disulfide.
J. Chem. Soc. , Chem. Commun.   24,1847-1848/,    1993
Synthesis of Partially Hydrogenated BINAP Ligands and Their Application to Catalytic Asymmetric Hydrogenation
J. Chem. Soc. , Perkin Trans. I   2309-2322   1994
Selective Formation of Ln(II) and Ln(III) Thiolate Complexes Derived From Metals and Organic Disulfides : Crystal Structures of [Ln(SAr)(μ-SAr)(thf)3]2 (Ln=Sm, Eu), Sm(SAr)3(py)2(thf), and Yb(SAr)3(py)3 (Ar=2,4,6-Triisopropylphenyl).
J. Chem. Soc. , Chem. Commun.   1847-1848   1994
Living polymerization of Ethylene Catalyzed by Diene Complexes of Niobium and Tantalum,M(η5-C5 Me5)-(η4-diene)X2 and M(η5-C5Me5)(η4-diene) 2 (・・・
Organometallics   14 2633   1995
Living polymerization of Ethylene Catalyzed by Diene Complexes of Niobium and Tantalum,M(η5-C5 Me5)-(η4-diene)X2 and M(η5-C5Me5)(η4-diene) 2</s...
Inorg, Chem   35(1) 93-99   1996
Synthesis of Arenethiolate Complexes of Divalent and Trivalent hanthanides from Metallic hanthanoides and Diaryl Disulfides : Crystal Structure of [{Yb(hmpa)3}2(μ-Sph)3][Sph] and Ln(Sph)3(hmpa)3</su...
Organometallics   15(10) 2431-2433   1996
Cis-iso-specific Polymerization of Nerbornenes by a Unique Combination of Cp* and 1,3-Butachine higands on Tantalum : Crystal Structures of Cp*Ta(η4-C4H6)Ta(CH2Ph)2 and C...
Theoretical Studies of Direct Exchange Couplings between Transition Metal Ions I. Naked Binuclear Chromium(II) and Molybdenum(II) Systems.
Mol. Cryst. Liq. Cryst.,   286 193-200   1996
Theoretical Studies of Direct Exchange Couplings between Transition Metal Ions II. Tetranuclear Transition Metal Systems.
Mol. Cryst. Liq. Cryst.,   286 201-210   1996
Group 4(Ti, Zr, Hf)Metal Compounds.
Synthesis of Organometallic Compounds : A Practical Guide,   75-97   1997
Chem. Lett.   (5) 411-412   1997
Large Third-Order Nonlinear Optical Susceptibilities of Multiply-Bonded M2(pyphos)4 and M2Pd2Cl2(pyphos)4(M=Cr, Mo ; Pyphos=6-Diphenylphosphino-2-pyridonate)by Picosecond Degenerate...
Organometallics   16(5) 1016-1025   1997
Chemistry of Coordinatively Unsaturated Bis(thiolato)Ruthenium(II)Complexes Ru(SAr)26-arene)[SAr=2,6-Dimethylbenzenethiolate, 2,4,6-Triisopropyl-benzenethiolate,(SAr)2=1,2-Benzenedithiolate ; arene=benzene, p-cym...
CASCI and CASSCF Studies of Dinuclear Transition Metal Systems with Quadruple Metal-Metal Bonds(M=Cr(II), Mo(II)).
Mol. Cryst. Liq. Cryst.   306 321-330   1997
Theoretical Studies of One Dimensional Tetranuclear Transition Metal Systems and Their Clusters.
Mol. Cryst. Liq. Cryst.   306 463-474   1997
J. Organomet. Chem.   545,546/,345-356/,    1997
Synthesis and Reactions of Coordinatively Unsaturated 16-Electron Chalcogenolate Complexes, Ru(EAr)26-arene), and Cationic Binuclear Chalcogenolate Complexes, [(η6-arene)Ru(μ-EPh)3Ru(η6-aren...
Kazushi Mashima, Hiromu Kaneyoshi, Sei-ichi Kaneko, Kazuhide Tani, Akira Nakamura
Chem. Lett.   (6) 569-570   1997
J. Organometal. Chem.   545,546/,549-552/,    1997
Recent Trend of Oligomerization of Alkenes, Alkynes, and Alkadienes Catalyzed by Organometallic Complexes(in Japanese).
Catalysts & Catalysis   39 645-653   1997
Nonplanar σ2, π-and Planar σ2-Enediamide Coordinations of 1,4-Di(p-methoxyphenyl)-1,4-diaza-1,3-butadiene(=MeOC6H4-DAD)on Ta(η5-C5R5)Fragments(R=H, Me) : Crystal Structures of・・・
Chem. Lett.   767-768   1997
Nonplanar σ2, π-and Planar σ2-Enediamide Coordinations of 1,4-Di(p-methoxyphenyl)-1,4-diaza-1,3-butadiene(=MeOC6H4-DAD)on Ta(η5-C5R5)Fragments(R=H, Me) : Crystal Structur...
Lanthanoid Complexes of Azobenzene and Benzo[c]cinnoline Derived From Metallic Lanthanoids : Crystal Structures of Monomeric Yb(cn)3(thf)2(cn=benzo[c]cinnoline)and Binucelar[SmI(μ-η2 : η2-PhNNPh)(thf)2</・・・
Chem. Lett.   803-804   1997
Lanthanoid Complexes of Azobenzene and Benzo[c]cinnoline Derived From Metallic Lanthanoids : Crystal Structures of Monomeric Yb(cn)3(thf)2(cn=benzo[c]cinnoline)and Binucelar[SmI(μ-η2 : η2-PhNNPh)(thf)<su...
Inorg. Chim. Acta   270(1/2) 459-466   1998
Unique Complexation by the Tridentate Ligands, 6-Diphenylphosphino-2-pyridonate(=pyphos)and 6-Diphenylphoshino-2-pyridone(=pyphosH), on Ruthenium((]G0002[)) : Crystal Structures of (pyphosH)RuC1(μ-CI)Mo2CI(pyphos)3, RuCl...
J. Organomet. Chem. ,   557 3-12   1998
Half-sandwich Complexes of Niobium and Tantalum Bearing o-Xylylene, Anthracene, or Cyclooctatetraene : Crystal Structures of (η5-C5Me5)Nb{o-(CH2)2C6H4}CI2,(η<s...
Activation and Stabilization of Organic Molecules by Tantalum-diene Fragment.
Reactive Organometallics,   403-406   1998
Organometallics   17(3) 410-414   1998
1,8-Diphenyl-octa-1,3,5,7-tetraene Complexes of Rutheninum((]G0002[)) : Crystal Structures of [μ-(s-cis-1,2,3,4-η : s-cis-5,6,7,8-η-PhCH=CHCH=CHCH=CHCH=CHPh)(RuClCp*)2]and[μ-(s-trans-1,2,3,4-η : s-trans-5,6,7,8-η-PhCH=CHCH=CHCH=CHCH=CHP...
Kazushi MASHIMA
J. Synth. Org. Chem. Jpn. ,   56(3) 171-181   1998
Masamichi Nishino, Yasunori Yoshioka, Kizashi Yamaguchi, Kazushi Mashima, Kazuhide Tani, Akira Nakamura
Bull. Chem. Soc. Jpn. ,   71(1) 99-112   1998
Polyhedron   17(7) 1065-1071   1998
Cationic Monocyclooctatetraenyl-lanthanoid Complexes Derived From Metallic Lanthanoid : Crystal Structures of [Sm(η8-C8H8)(hmpa)3]I and [Sm(η8-C8H8)(hmpa)3][Sm...
J. Organometal. Chem.   559(1/2) 197-201   1998
Mononuclear η8-Cyclooctatetraenyl(thiolato)samarium((]G0003[)) Complexes (η8-C8H8)Sm(SR)(hmpa)2(R=2,4,6-Triisopropylphenyl and 2-Pyridyl ; HMPA=Hexamethylphosphoric Triamide)Derived from Metal...
J. Organometal. Chem. ,   566(1/2) 111-116   1998
Polymerization of Ethylene by Half-metallocene Complexes of Nioblium, Tantalum, and Zirconium Bearing o-Xylylene or Anthracene As an Auxiliary Ligand : Molecular Structure of [Mg2Cl3(thf)6][ZrCl25...
J. Org. Chem. ,   63(20) 7114-7116   1998
The First Oxidative Addition of a Hypervalent Compound to Metallic Lanthanoid : Synthesis, Characterization, and Reaction of Samarium((]G0002[)) Bistrifluoromethanesulfonate Derived from Metallic Samarium and 1,5-Dithioniabicyclo[3.3.0]octane Bis(...
Proc. Japan Academy.   74 217-220   1998
Polymerization of Methyl Methacrylate Catalyzed by Tantalum-diene Complexes, Ta(η5C5R5)-(η4-1,3-butadiene)2(R=H and Me)in the Presence of Cocatalyst AlMe(OC6H2-2,6-(tBu)<...
Novel Synthesis of hanthanoid Complexes Starting from metallic hanthanoid Sources
J.Chem.Soc.,Dalton Trans.   3899-3907   1999
Convenient Synthesis of Anionic Dinuclear Ruthenium((]G0002[))Complexes[NH2R2][{RuCl(diphosphine)}2-(μ-Cl)2][diphosphine=2, 2'-bis(diphenylphosphino)-1, 1'-binaphtyl and 1, 2-bis(diphenylphosphins)benzene].
J. Organometallic Chemistry   607 51-56   2000
Yutaka Matsuo, Kazushi Mashima, Kazuhide Tani
Chem. Lett.   (10) 1114-1115   2000
Half-metallocene 1- Aza-1.3-butadiene Complexes of Tantalum : Auxiliary Ligand Ettects on Controlling Coordination modes of 1-Aga-1.3-butadiene Ligand
B.C.S.J.   75, 1291-1297/,    2002

Books etc

 
New BINAP-Ru(II) Complexes for Asymmetric Catalytic Hydrogenation
ACS Symposium Series   1992   
Extended dπ-pπ Conjugation in Organometallic Complexes
Organometallic π-Corylugated Systems   2000   
Tantalum Organometallics in Comprehensive Organometallic Chemistry-III
K. Mashima (Part:Joint Work)
Elsevier   Dec 2006   

Research Grants & Projects

 
Synthesis of Organolanthanide Complexes
Synthesis of One-dimensional Metal Clusters
Polymerization Catalyzed by Diene Complexes of Group 5 Metals
Asymmetric Reactions Catalyzed by Transition Metal Complexes
Immobilization Catalysts and Surface Modification

Patents

 
Third-order Nonlinear Optical Material
*
Preparation of cyclopentadiene transition metal complexes as catalysts for preparation of optically active benzyl alcohols
*
Ruthenium bis(diphenylphosphino)binaphthyl complexes as asymmetric hydrogenation catalysts H.Takaya, K.Mashima, H.Kumobayashi, and N.Sayo
European patent, 89310901.7-(1989).
Japanese patent(1990).
Bis(diphenylphosphino)cyclopentane Derivatives and Their Transition Metal Complexes. H.Takaya and K.Mashima
Iridium-optically Active Phosphine Complex and Catalytic Producation of Optically Active Alcohols therewith. T.Taketomi, S.Akutagawa, H.Kumobayashi, K.Mashima, and H.Takaya
European Patent, 91308956.1-(1991).
Third-order Nonlinear Optical Material. T.Sakaguchi, K.Ohta, A.Nakamura, and K.Mashima
US Patent 5,961,890(1999).