2007年12月
Benzylation of alpha-diimine ligands bound to zirconium and hafnium. A new convenient route to olefin polymerization catalysts
CHEMISTRY LETTERS
- ,
- ,
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- 巻
- 36
- 号
- 12
- 開始ページ
- 1420
- 終了ページ
- 1421
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1246/cl.2007.1420
- 出版者・発行元
- CHEMICAL SOC JAPAN
Reactions of M(CH2Ph)(4) (M = Zr and Hf) with alpha-diimine ligands 1 at -78 degrees C selectively afford tribenzyl amido-imino complexes of zirconium 4 and hafnium 5, whose treatment with B(C6F5)(3) gave the corresponding cationic dibenzyl complexes 6 and 7 capable of polymerizing 1-hexene.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.2007.1420
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000251854700008