論文

査読有り
2012年3月

Effects of side-chain ends on the stiffness and excluded-volume parameters of polymacromonomers

POLYMER JOURNAL
  • Hidetsugu Kanda
  • ,
  • Yo Nakamura

44
3
開始ページ
252
終了ページ
256
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/pj.2011.132
出版者・発行元
NATURE PUBLISHING GROUP

Light and small-angle X-ray scattering measurements were taken on cyclohexane and toluene solutions of a polystyrene (PS) polymacromonomer (PM) having side chains consisting of 19 styrene residues and an n-butyl group (butyl-PS PM) at each end. The second virial coefficient, A(2), of the butyl-PS PM in cyclohexane was positive in the temperature range of 15.0-34.5 degrees C, differing from previous results for PS PMs with benzyl ends (benzyl-PS PM) whose A(2) vanished at 34.5 degrees C. The mean-square radius of gyration, < S-2 >, for the butyl-PS PM in cyclohexane at 34.5 degrees C was much larger than that for the benzyl-PS PM with the same side-chain length, indicating large effects of the side-chain ends on intramolecular interactions, whereas the difference in < S-2 > between these polymers in toluene at 15.0 degrees C was quite small. From these data, the stiffness parameter and the excluded-volume strength were determined with the aid of theories for the wormlike chain model. The effects of the side-chain ends on these parameters are discussed according to recently developed theories. Polymer Journal (2012) 44, 252-256; doi:10.1038/pj.2011.132; published online 14 December 2011

リンク情報
DOI
https://doi.org/10.1038/pj.2011.132
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000301193400008&DestApp=WOS_CPL
ID情報
  • DOI : 10.1038/pj.2011.132
  • ISSN : 0032-3896
  • Web of Science ID : WOS:000301193400008

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