MISC

筆頭著者 責任著者
1995年

単分散超微粒子懸濁液の線形粘弾性挙動

日本レオロジー学会誌
  • 四方俊幸
  • ,
  • 小高忠男

23
2
開始ページ
81
終了ページ
87
記述言語
日本語
掲載種別
DOI
10.1678/rheology1973.23.2_81
出版者・発行元
一般社団法人 日本レオロジー学会

Linear viscoelastic behavior was examined for suspensions of an ultra-fine silica particle, S7.5, with a radius of 7.5nm dispersed in highly viscous medium consisting of ethylene glycole and glycerin, and was compared with that of previously examined suspensions with radii larger than S7.5. A S7.5, system exhibited remarkable viscoelasticity as well as systems with larger radii, and the zero-shear viscosity, η0, the high frequency limiting viscosity, η′, and the high frequency limiting modulus, G, could be estimated. However, the dependence of η0 and η′ on particle concentration for the S7.5 system was completely different from universal one holding in the larger particle systems independently of particle radii. The size of the S7.5 is so small, that the contribution of a special interface layer formed by interacting medium molecules with the surface of the S7.5 to gross rheology becomes important in contradiction to the larger particle systems. The relationship between η0′ and patticle volume fraction, φ, holding in the larger particle systems which are hard-core suspensions was extended to the S7.5 system. Then, the effective volume fraction, φeff, and the effective medium viscosity, ηm+, for the S7.5 system was estimated by rescaling the system to an equivalent hard core suspension system. The average relaxation time for the system could be successfully regulated by the φeff not by φ, however, the G could be simply governed by the original φ just like found in the hard core suspensions.

リンク情報
DOI
https://doi.org/10.1678/rheology1973.23.2_81
CiNii Articles
http://ci.nii.ac.jp/naid/130004703582
URL
https://jlc.jst.go.jp/DN/JALC/10016259361?from=CiNii
ID情報
  • DOI : 10.1678/rheology1973.23.2_81
  • ISSN : 0387-1533
  • CiNii Articles ID : 130004703582

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