1999年6月
Kinetics and mechanism of the oxidation of [Fe(CN)6]4- to [Fe(CN)6]3-, induced by the reaction between Cu2+ and I- in aqueous solution. Oxidation reaction by a radical anion I2-·
Bulletin of the Chemical Society of Japan
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- ,
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- 巻
- 72
- 号
- 6
- 開始ページ
- 1293
- 終了ページ
- 1299
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1246/bcsj.72.1293
The hexacyanoferrate(II) ion ([Fe(CN)6]4-) was rapidly oxidized to [Fe(CN)6]3- by a radical anion, I2-·, which was formed by a reaction between the copper(II) ion and the iodide ion. The oxidation reaction was accelerated by increasing the pH. Under the conditions of lower pH's, the [Fe(CN)6]3- acted as a retarder to the oxidation reaction. The mechanisms for such reactions are discussed in terms of accounting for the obtained results.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.72.1293
- ISSN : 0009-2673
- SCOPUS ID : 0032991758