Yutaka Nishigaichi - My portal - researchmap

Profile Information

Affiliation: Interdisciplinary Faculty of Science and Engineering, Department of Chemistry, Shimane University

Degree: (BLANK)

J-GLOBAL ID: 200901005119762804
researchmap Member ID: 1000034892

Research Interests

4

Research Areas

2

Research History

1

Associate Professor, Shimane University Interdisciplinary Faculty of Science and Engineering, Department of Material Science

Papers

19

Synthesis of 5,10-bis(Trifluoromethyl) Substituted beta-Octamethylporphyrins and Central-Metal-Dependent Solvolysis of Their meso-Trifluoromethyl Groups

Masaaki Suzuki, Saburo Neya, Yutaka Nishigaichi

MOLECULES, 21(3) 252, Mar, 2016 Peer-reviewed
Photochemically Assisted Introduction of a Benzyl Unit into Isoquinolines Using Benzyltrifluoroborates

Nishigaichi Yutaka, Orimi Takayuki, Koyachi Kuniyoshi, Ohmuro Yuuki, Suzuki Masaaki

Chemistry Letters, 45(12) 1382-1384, 2016 Peer-reviewed
Allyl-transfer Reaction from Photoexcited Hypervalent Allylsilicon Reagent toward Dicyanobenzenes

Daisuke Matsuoka, Yutaka Nishigaichi

CHEMISTRY LETTERS, 44(2) 163-165, Feb, 2015 Peer-reviewed
Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer

Daisuke Matsuoka, Yutaka Nishigaichi

CHEMISTRY LETTERS, 43(4) 559-561, Apr, 2014 Peer-reviewed
Regio-controlled pentadienylation of sulfinylimines by pentadienyltin reagent. Efficient Lewis acid activation of 4-methoxyphenylsulfinyl imines

Yutaka Nishigaichi, Shinji Tsuruta, Kenji Uenaga, Tomohiko Awamura, Hidetoshi Iwamoto, Akio Takuwa

TETRAHEDRON LETTERS, 55(2) 510-513, Jan, 2014 Peer-reviewed
An Enantiodivergent Synthesis of (+)- and (–)-Centrolobines via the Asymmetric Esterification Catalyzed by (R)-(+)-N-Methylbenzoguanidine ((R)-NMBG)

Kenya NAKATA, Tatsuya TOKUMARU, Hidetoshi IWAMOTO, Yutaka NISHIGAICHI, Isamu SHIINA

Asian Journal of Organic Chemistry, 2 920-922, Nov, 2013 Peer-reviewed
Binary 1,4-asymmetric induction toward imines from a single allyltin reagent with a chiral oxygen functional group

Yutaka Nishigaichi, Takahiro Fujimoto, Akio Takuwa, Hidetoshi Iwamoto

TETRAHEDRON LETTERS, 51(48) 6298-6300, Dec, 2010 Peer-reviewed
Reversible stereocontrol in the Lewis acid promoted reaction of alkoxyaldehydes toward various allyltins

Y Nishigaichi, A Takuwa

TETRAHEDRON LETTERS, 44(7) 1405-1408, Feb, 2003 Peer-reviewed
Stereospecific formation of deuterated homoallyl alcohols by Lewis acid-promoted reactions of allyltin and allylsilicon reagents toward aldehydes

Y Nishigaichi, A Takuwa

TETRAHEDRON LETTERS, 43(16) 3045-3047, Apr, 2002 Peer-reviewed
Regioselective allylation of 1,2-naphthoquinones using photoaddition reaction with allylsilanes: Synthesis of 3-allyl-1,2-naphthoquinones

A Takuwa, T Sasaki, H Iwamoto, Y Nishigaichi

SYNTHESIS-STUTTGART, (1) 63-68, Jan, 2001 Peer-reviewed
Asymmetric catalysis with chiral Lewis bases

SE Denmark, RA Stavenger, XP Su, KT Wong, Y Nishigaichi

PURE AND APPLIED CHEMISTRY, 70(8) 1469-1476, Aug, 1998 Peer-reviewed
CONJUGATE ADDITION OF ALLYLIC GROUPS TO ALPHA,BETA-ENONES VIA PHOTOINDUCED ELECTRON-TRANSFER REACTION OF ALLYLIC STANNANES

A TAKUWA, Y NISHIGAICHI, H IWAMOTO

CHEMISTRY LETTERS, (6) 1013-1016, Jun, 1991 Peer-reviewed
ALLYLATION OF ALPHA-DIKETONES BY PHOTOCHEMICAL-REACTIONS WITH ALLYLIC STANNANES - REGIOCHEMISTRY OF INTRODUCED ALLYLIC GROUP

A TAKUWA, Y NISHIGAICHI, K YAMASHITA, H IWAMOTO

CHEMISTRY LETTERS, (4) 639-642, Apr, 1990 Peer-reviewed
OPTICALLY-ACTIVE PENTADIENYLTIN REAGENT AND ITS APPLICATION TO ASYMMETRIC-SYNTHESIS OF (R)-7,11-DIDEOXYDAUNOMYCINONE

Y NARUTA, Y NISHIGAICHI, K MARUYAMA

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, (17) 1203-1205, Sep, 1989 Peer-reviewed
SYNTHESIS OF NATURALLY-OCCURRING QUINONES .21. AN EFFICIENT ASYMMETRIC-SYNTHESIS OF 11-DEOXYANTHRACYCLINONE

Y NARUTA, Y NISHIGAICHI, K MARUYAMA

TETRAHEDRON LETTERS, 30(25) 3319-3322, 1989 Peer-reviewed
CONTROL OF GAMMA-REGIOSELECTIVITY VS EPSILON-REGIOSELECTIVITY ON THE NUCLEOPHILIC-ADDITION OF 2,4-PENTADIENYLSTANNANE TO ALDEHYDES BY LEWIS ACID COORDINATION

Y NARUTA, Y NISHIGAICHI, K MARUYAMA

CHEMISTRY LETTERS, (2) 225-228, Feb, 1988 Peer-reviewed
REGIOSELECTIVE AND STEREOSELECTIVE TRAPPING OF PENTADIENYL ANION BY A TIN ELECTROPHILE

Y NARUTA, Y NISHIGAICHI, K MARUYAMA

CHEMISTRY LETTERS, (1) 135-138, Jan, 1988 Peer-reviewed
SYNTHESIS OF NATURALLY-OCCURRING QUINONES .18. TRICHLORO-(TRANS-2,4-PENTADIENYL)STANNANE AS A LESS ELECTRON-RICH DIENE AND ITS APPLICATION TO TANDEM MICHAEL-DIELS-ALDER REACTIONS - FORMAL TOTAL SYNTHESIS OF 11-DEOXYDAUNOMYCINONE

Y NARUTA, Y NISHIGAICHI, K MARUYAMA

CHEMISTRY LETTERS, (10) 1703-1706, Oct, 1986 Peer-reviewed
SYNTHESIS OF NATURALLY-OCCURRING QUINONES .14. SYNTHESIS OF 11-DEOXYANTHRACYCLINONE PRECURSOR - A NEW STRATEGY TOWARD TETRACYCLIC SYSTEM VIA TANDEM 1,4/[4+2] ADDITION

Y NARUTA, M KASHIWAGI, Y NISHIGAICHI, H UNO, K MARUYAMA

CHEMISTRY LETTERS, (11) 1687-1690, 1983 Peer-reviewed

Misc.

43

不斉エステル化反応を鍵工程とするセントロロビンの二方向性合成

中田健也, 徳丸達也, 岩本秀俊, 西垣内寛, 椎名勇

有機合成シンポジウム講演要旨集, 104th 112-113, Oct 28, 2013
Photo-allylation and photo-benzylation of carbonyl compounds using organotrifluoroborate reagents

Yutaka Nishigaichi, Takayuki Orimi, Akio Takuwa

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694(24) 3837-3839, Nov, 2009
Binary 1,4-asymmetric induction from a single allyltin reagent with a chiral nitrogen functional group toward aldehydes

Yutaka Nishigaichi, Ken-ichi Tamura, Narifumi Ueda, Hidetoshi Iwamoto, Akio Takuwa

TETRAHEDRON LETTERS, 49(13) 2124-2127, Mar, 2008
Remarkable enhancement of photo-allylation of aromatic carbonyl compounds with a hypervalent allylsilicon reagent by donor molecules

Yutaka Nishigaichi, Akira Suzuki, Akio Takuwa

TETRAHEDRON LETTERS, 48(2) 211-214, Jan, 2007
Molecular cloning, functional expression, and tissue distribution of a potato sprout allene oxide synthase involved in a 9-lipoxygenase pathway

Darika Kongrit, Mitsuo Jisaka, Kazuhiro Kobayasi, Yutaka Nishigaichi, Kohji Nishimura, Tsutornu Nagaya, Kazushige Yokota

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 70(9) 2160-2168, Sep, 2006
Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects

SE Denmark, SM Pham, RA Stavenger, XP Su, KT Wong, Y Nishigaichi

JOURNAL OF ORGANIC CHEMISTRY, 71(10) 3904-3922, May, 2006
Highly efficient binary and remote asymmetric induction from a single allyltin reagent with a chiral carbamate moiety

Y Nishigaichi, N Ueda, K Tamura, A Takuwa

SYNLETT, 2005(16) 2519-2521, Oct, 2005
First examples of hypervalent enhancement of photoallylation by allylsilicon compounds via photoinduced electron transfer

Y Nishigaichi, A Suzuki, T Saito, A Takuwa

TETRAHEDRON LETTERS, 46(31) 5149-5151, Aug, 2005
Binary regiocontrol in the reaction between pentadienyltin and imines by Lewis acids and N-substituents

Y Nishigaichi, M Ishihara, S Fushitani, K Uenaga, A Takuwa

CHEMISTRY LETTERS, 33(2) 108-109, Feb, 2004
Allylsilylation and stannylation of 1,2-diketones using bifunctional allylsilane-allylstannane reagents via photoinduced electron transfer reaction

A Takuwa, H Saito, Y Nishigaichi

CHEMICAL COMMUNICATIONS, (19) 1963-1964, Oct, 1999
Contrasting regiochemistry in thermal and photochemical allylstannations of 1,2-naphthoquinone

Y Nishigaichi, N Yoshida, M Matsuura, A Takuwa

CHEMISTRY LETTERS, (8) 803-804, Aug, 1999
Synthesis of phosphoramides for the Lewis base-catalyzed allylation and aldol addition reactions

SE Denmark, YP Su, Y Nishigaichi, DM Coe, KT Wong, SBD Winter, JY Choi

JOURNAL OF ORGANIC CHEMISTRY, 64(6) 1958-1967, Mar, 1999
Stereospecificity in the Lewis acid promoted allylation reaction of 3,3-disubstituted allyltins toward aldehydes

Y Nishigaichi, A Takuwa

TETRAHEDRON LETTERS, 40(1) 109-112, Jan, 1999
The chemistry of trichlorosilyl enolates. 6. Mechanistic duality in the Lewis base-catalyzed aldol addition reaction

SE Denmark, XP Su, Y Nishigaichi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 120(49) 12990-12991, Dec, 1998
Stereoretentive introduction of (E)- and (Z)-gamma-alkoxyallyl groups into carbonyl compounds via light-promoted reaction with gamma-alkoxyallylstannanes

A Takuma, Y Nishigaichi, S Ebara, H Iwamoto

CHEMICAL COMMUNICATIONS, (17) 1789-1790, Sep, 1998
Photochemical 1,3-stannyl rearrangement of allylic stannanes

A Takuwa, T Kanaue, K Yamashita, Y Nishigaichi

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 7(7) 1309-1314, Apr, 1998
Simultaneous control of regio- and stereochemistries in the reaction between alpha-alkoxyaldehydes and pentadienyltin. Selective preparations of the four regio- and diastereoisomers

Y Nishigaichi, Y Hanano, A Takuwa

CHEMISTRY LETTERS, (1) 33-34, 1998
Lewis acid-mediated addition of 1,2-naphthoquinones with 1,1-diarylethylenes and photocyclization of the adducts: A facile synthesis of 3,12-disubstituted chrysene-5,6-diones

A Takuwa, Kameoka, I, A Nagira, Y Nishigaichi, H Iwamoto

JOURNAL OF ORGANIC CHEMISTRY, 62(8) 2658-2661, Apr, 1997
Substituent-control of stereoselectivity in the reaction of allylic tins. Anti-selective Lewis acid-promoted reaction toward aldehydes

Y Nishigaichi, N Ishida, M Nishida, A Takuwa

TETRAHEDRON LETTERS, 37(21) 3701-3704, May, 1996
New formal [3+2] photoaddition of vinyl ethers to o-benzoquinones

A Takuwa, R Kai, K Kawasaki, Y Nishigaichi, H Iwamoto

CHEMICAL COMMUNICATIONS, (6) 703-704, Mar, 1996

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Books and Other Publications

1

はじめての有機スペクトル解析

丸善, 2004 (ISBN: 4621075055)

Presentations

87

カルボニル化合物とベンジルケイ素試剤との光反応におけるシリル基の置換基効果

日本化学会第90春期年会, 2010
インジウム塩とブレンステッド酸の同時添加によるN-スルフィニルイミンの活性化

日本化学会第90春期年会, 2010
不斉点にカルバミン酸エステルを導入したアリルスズ試剤からの二方1,4-遠隔不斉誘導反応の制御

日本化学会第90春期年会, 2010
不斉酸素官能基をもつアリルスズからの遠隔不斉誘導反応生成物の合成的活

日本化学会第90春期年会, 2010
チオメチルケイ素試剤による光誘起一電子移動を経由した芳香族ケトン類のチオメチル化反応

日本化学会第90春期年会, 2010
4配位ホウ素試剤によるイソキノリニウム塩への光誘起付加反応を経由したベンジルイソキノリンアルカロイド類の合成

日本化学会第90春期年会, 2010
ルイス酸に亜鉛化合物を用いた不斉酸素官能基をもつアリルスズとアルデヒドとの1,5-遠隔不斉誘導反応

日本化学会第90春期年会, 2010
芳香族カルボニル化合物の光アリル化反応における高配位アリルシリコネートの配位子の影響

日本化学会第90春期年会, 2010
光アリル化反応における高配位型アリルシリコネートの配位子の影響

日本化学会西日本大会, 2009
Photochemical Synthesis of Benzylisoquinoline Derivatives Using Tetra-coordinated Benzylborates

The 11th International Kyoto Conference on New Aspects of Organic Chemistry, 2009
金属イオンによるアリルスズ/アミノメチルケイ素反応剤の光一電子移動反応性の制御

日本化学会第89春季年会, 2009
4配位有機ホウ素試剤を用いたイソキノリニウム塩への光及び熱的求核付加反応

日本化学会第89春季年会, 2009
水溶液中におけるカルボニル化合物とケイ素試剤との光付加反応

日本化学会第89春季年会, 2009
Nucleophilic photo-alkylation reaction with hypervalent alkyltin reagents

第56回有機金属化学討論会, 2009
Structural influence of silyl group on photobenzylation reaction of α-diketones with benzylsilane reagents

第56回有機金属化学討論会, 2009
Substituent effect on 1,4-remote asymmetric induction from allyltin reagents containing a chiral functionality toward sulfonylimine

第56回有機金属化学討論会, 2009
α-ジケトンとベンジルケイ素試剤との光電子移動ベンジル化反応

日本化学会西日本大会, 2008
ナフトール類の自動酸化によるアリール-アリール結合形成反応

日本化学会西日本大会, 2008
N-スルフィニルイミンとペンタジエニルスズとの位置選択的反応におけるルイス酸の濃度効果

日本化学会西日本大会, 2008
側鎖に機能をもたせた高配位ブチルスタナトランによる光ブチル化反応

日本化学会西日本大会, 2008

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Works

9

Research Projects

2