2009年5月
Synthesis of Bioactive HEMA-MPS-CaCl2 Hybrid Gels: Effects of Catalysts in the Sol-Gel Processing on Mechanical Properties and in vitro Hydroxyapatite Formation in a Simulated Body Fluid
JOURNAL OF BIOMATERIALS APPLICATIONS
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- 巻
- 23
- 号
- 6
- 開始ページ
- 519
- 終了ページ
- 532
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1177/0885328208094262
- 出版者・発行元
- SAGE PUBLICATIONS LTD
We investigated synthetic conditions for the fabrication of bioactive hybrid gels from monomers of 2-hydroxyethylmethacrylate ( HEMA) and 3-methacryloxypropyltrimethoxysilane (MPS) in combination with CaCl2, at a starting molar ratio of HEMA: MPS: CaCl2 of 9:1:1. Hydroxyapatite formation, essential to show bone bonding, was observed on the HEMA-MPS-CaCl2 hybrid gels with the added catalysts NH3 or HCl with a molar ratio to MPS of 0.1, but not on the hybrid gel with HCl at a molar ratio to MPS of 1. The mechanical properties of the gels were dependent on the catalysts, which may affect the microstructures that develop during sol-gel processing.
- リンク情報
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- DOI
- https://doi.org/10.1177/0885328208094262
- CiNii Articles
- http://ci.nii.ac.jp/naid/120002443256
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/18757494
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000265750300003&DestApp=WOS_CPL
- ID情報
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- DOI : 10.1177/0885328208094262
- ISSN : 0885-3282
- eISSN : 1530-8022
- CiNii Articles ID : 120002443256
- PubMed ID : 18757494
- Web of Science ID : WOS:000265750300003