1992年9月
ESR-SPECTRA OF SOME ALLENE RADICALS IN LOW-TEMPERATURE MATRICES
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- 巻
- 65
- 号
- 9
- 開始ページ
- 2442
- 終了ページ
- 2449
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.65.2442
- 出版者・発行元
- CHEMICAL SOC JAPAN
ESR spectra of the radicals of allene (1,2-propadiene) derivatives generated by Co-60 gamma-ray irradiation in halocarbon matrices have been observed at low temperatures. The geometrical structures of the radicals have been determined from the experimental ESR spectra and with the aid of semiempirical MO calculations invoking the UHF-AM1 and UHF-MNDO methods. After exposure of the allene derivatives to Co-60 gamma-ray in some halocarbon matrices at 77 K, the temperature raising gave rise to neutral radicals such as allylic and/or deprotonation-type radicals; these thermal reactions have been investigated in detail.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.65.2442
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:A1992JP92100023