1997年
ポルトランド石の空気中加熱により生成する方解石-温室効果防止を目的とする地球規模二酸化炭素固定回収工場の設立をめざして。
鉱物学雑誌
- ,
- ,
- 巻
- 26
- 号
- 3
- 開始ページ
- 129
- 終了ページ
- 134
- 記述言語
- 日本語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.2465/gkk1952.26.129
- 出版者・発行元
- Japan Association of Mineralogical Sciences
Carbonation of slaked lime, mineral name portlandite, has been studied in air at moderately high temperatures ranging from 200°C to 550°C with variable heating time up to 72 h. Formation of calcite was observed for every run, accompanied with some remaining portlandite at low temperatures and quicklime at high temperatures due to surface-limited reaction between source materials and carbon dioxide included in air as much as 330-340 ppm. The maximum yield of calcite was 73.3 percent in the experimental condition. The 51.1 percent yield reached by 450°C heating in 6 h is regarded to have a high potential of practical applications for preventing the greenhouse effect. The reaction rate resulted were interpreted in terms of kinetics, applying the Jander equation. As a consequence, 125.7 kJ/mol was obtained for the apparent activation energy of reaction by the Arrehnius plots.
- リンク情報
- ID情報
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- DOI : 10.2465/gkk1952.26.129
- ISSN : 0454-1146
- CiNii Articles ID : 130003623848