論文

査読有り
2003年9月

Displacive character of the paraelectric-ferroelectric phase transition in K2ZnI4

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
  • H Kasano
  • ,
  • H Mashiyama

72
9
開始ページ
2236
終了ページ
2242
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1143/JPSJ.72.2236
出版者・発行元
PHYSICAL SOC JAPAN

The crystal structure of K2ZnI4 is refined at 24 temperatures above and below the paraelectric-ferroelectric phase transition temperature by means of X-ray diffraction to reinvestigate the mechanism of the phase transition in more detail. The temperature dependence of the translation of K(1) and K(2) along the b-axis and the rotational angle of the ZnI4 tetrahedron about the axis nearly parallel to the a-axis is obtained by the structural analyses. It is concluded that the mechanism of this phase transition is not the order-disorder type but the displacive one. The temperature variation of the anisotropic temperature parameter U-22 of K(1), K(2), I(1) and I(2) is coincident with the theoretical prediction for the displacive type phase transition proposed by Fujii and Matsubara [Prog. Theor. Phys. 78 (1987) 177].

リンク情報
DOI
https://doi.org/10.1143/JPSJ.72.2236
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000185540600022&DestApp=WOS_CPL
ID情報
  • DOI : 10.1143/JPSJ.72.2236
  • ISSN : 0031-9015
  • Web of Science ID : WOS:000185540600022

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