2004年11月
Deuterated analogues of 4,8-dimethyldecanal, the aggregation pheromone of Tribolium castaneum: synthesis and pheromonal activity
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS
- ,
- ,
- 巻
- 47
- 号
- 13
- 開始ページ
- 921
- 終了ページ
- 934
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1002/jlcr.881
- 出版者・発行元
- JOHN WILEY & SONS LTD
To elucidate the deuterium isotope effect (DIE) in pheromonal activity and to investigate the biosynthetic pathway of 4,8-dimethyldecanal (4,8-DMD; 1), the aggregation pheromone of the red flour beetle (Tribolium castaneum), deuterated analogues of 4,8-DMDs (2, 3, 4, and 5), were synthesized and their pheromonal activities were tested using a two-hole pitfall olfactometer. Although no apparent DIE was observed in their pheromonal activities, 4,8-DMD-1-d(1) (2) was less attractive than other analogues, which suggested that the bond distance between the formyl group of I and its receptor was critical in pheromone recognition by T. castaneum. Copyright (C) 2004 John Wiley Sons, Ltd.
- リンク情報
- ID情報
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- DOI : 10.1002/jlcr.881
- ISSN : 0362-4803
- Web of Science ID : WOS:000225657600003