MISC

2010年5月

Dissakisite-(Ce) chemical composition: some implications for its origins

PHYSICS AND CHEMISTRY OF MINERALS
  • Mihoko Hoshino
  • ,
  • Mitsuyoshi Kimata
  • ,
  • Norimasa Nishida
  • ,
  • Masahiro Shimizu

37
5
開始ページ
255
終了ページ
263
記述言語
英語
掲載種別
DOI
10.1007/s00269-009-0329-8
出版者・発行元
SPRINGER

Euhedral dissakisites from Trimouns dolomite mine, France, is compositionally zoned. Back-scattered electron (BSE) images reveal that each of the described dissakisite crystals has three distinct compositional zones: normal zoned core (Mg-rich), oscillatory zoned middle (Ca-Al-rich) and homogeneous rim (Fe-I REE-rich) pound. The latter zone with Fe(2+) > Mg corresponds to allanite-(Ce). Dissakisite-(Ce) also displays pronounced zoning in Fe/Mg which may suggest that the temperature of crystallization continuously decreased from core to rim. Despite a systematic increase in Fe/Mg of the dissakisite with an allanite rim, there is no monotonic decrease in the REE zoning: the normal zoned core and homogeneous rim are rich in La, Ce and Pr, but the relatively REE-poor oscillatory zoned middle is relatively abundant in Y, Sm and Gd. Discontinuous variation in REE content of the dissakisite, with the allanite rim may indicate a localized change in either the relative concentration of various ligands or pH of the crystallizing fluid. Observations under the polarizing microscope confirm that the different zones have simultaneous extinction. These chemical and optical observations suggest that epitaxial crystallization of dissakisite, from Trimouns, passes through three formation stages. The ternary Fe(2+)-Mg(2+)-(Al + Fe)(3+) diagram illustrates that in general dissakisite can be classified into two groups, (Al + Fe)(3+)-rich and an Mg-rich; dissakisite from Trimouns belongs to the former group. Chondrite-normalized REE patterns of dissakisites from Trimouns are similar to those of allanites formed by hydrothermal fluids. In conclusion, it is clear from the above two geochemical characteristics that dissakisites from Trimouns are of (Al + Fe)(3+)-type, and were derived from hydrothermal fluids.

リンク情報
DOI
https://doi.org/10.1007/s00269-009-0329-8
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000277098000001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1007/s00269-009-0329-8
  • ISSN : 0342-1791
  • Web of Science ID : WOS:000277098000001

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