2019年
Active Sites and Mechanism of Oxygen Reduction Reaction Electrocatalysis on Nitrogen-Doped Carbon Materials
Advanced materials (Deerfield Beach, Fla.)
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- ,
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- 巻
- 13
- 号
- 13
- 開始ページ
- 1804297
- 終了ページ
- 1804297
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/adma.201804297
The oxygen reduction reaction (ORR) is a core reaction for electrochemical energy technologies such as fuel cells and metal-air batteries. ORR catalysts have been limited to platinum, which meets the requirements of high activity and durability. Over the last few decades, a variety of materials have been tested as non-Pt catalysts, from metal-organic complex molecules to metal-free catalysts. In particular, nitrogen-doped graphitic carbon materials, including N-doped graphene and N-doped carbon nanotubes, have been extensively studied. However, due to the lack of understanding of the reaction mechanism and conflicting knowledge of the catalytic active sites, carbon-based catalysts are still under the development stage of achieving a performance similar to Pt-based catalysts. In addition to the catalytic viewpoint, designing mass transport pathways is required for O . Recently, the importance of pyridinic N for the creation of active sites for ORR and the requirement of hydrophobicity near the active sites have been reported. Based on the increased knowledge in controlling ORR performances, bottom-up preparation of N-doped carbon catalysts, using N-containing conjugative molecules a
- リンク情報
- ID情報
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- DOI : 10.1002/adma.201804297
- ISSN : 1521-4095