論文

査読有り
2019年

Active Sites and Mechanism of Oxygen Reduction Reaction Electrocatalysis on Nitrogen-Doped Carbon Materials

Advanced materials (Deerfield Beach, Fla.)
  • Singh
  • ,
  • Santosh K
  • ,
  • Takeyasu, Kotaro
  • ,
  • Nakamura, Junji

13
13
開始ページ
1804297
終了ページ
1804297
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/adma.201804297

The oxygen reduction reaction (ORR) is a core reaction for electrochemical energy technologies such as fuel cells and metal-air batteries. ORR catalysts have been limited to platinum, which meets the requirements of high activity and durability. Over the last few decades, a variety of materials have been tested as non-Pt catalysts, from metal-organic complex molecules to metal-free catalysts. In particular, nitrogen-doped graphitic carbon materials, including N-doped graphene and N-doped carbon nanotubes, have been extensively studied. However, due to the lack of understanding of the reaction mechanism and conflicting knowledge of the catalytic active sites, carbon-based catalysts are still under the development stage of achieving a performance similar to Pt-based catalysts. In addition to the catalytic viewpoint, designing mass transport pathways is required for O . Recently, the importance of pyridinic N for the creation of active sites for ORR and the requirement of hydrophobicity near the active sites have been reported. Based on the increased knowledge in controlling ORR performances, bottom-up preparation of N-doped carbon catalysts, using N-containing conjugative molecules a

リンク情報
DOI
https://doi.org/10.1002/adma.201804297
URL
https://onlinelibrary.wiley.com/doi/am-pdf/10.1002%2Fadma.201804297
URL
http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201804297/fullpdf
ID情報
  • DOI : 10.1002/adma.201804297
  • ISSN : 1521-4095

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