論文

査読有り
2004年

Preparation of styryl-ended rod-like poly(n-hexyl isocyanate) macromonomers and their radical co-polymerization behavior with styrene

DESIGNED MONOMERS AND POLYMERS
  • M Kikuchi
  • ,
  • S Kawaguchi
  • ,
  • K Nagai

7
6
開始ページ
603
終了ページ
617
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1163/1568555042474158
出版者・発行元
VSP BV

Styryl-ended rod-like macromonomers consisting, of poly(n-hexyl isocyanate) (2) (VB-HIC-n, where n is a degee of polymerization varying from 9 to 75) with relatively narrow molecular weight distribution (M-w/M-n < 1.2) have successfully been prepared in CH2Cl2 at room temperature by living coordination polymerization of n-hexyl isocyanate (HIC) using 4-vinvibenzyloxy-dichloro(cyclopentadienyl)titanium(IV) (1) as an initiator. The radical co-polymerization behavior of the rod-like macromonorners with styrene has been studied and summarized as a function of degree of polymerization of HIC. The apparent co-polymerizabilities of the rod-like macromonomer seem to be almost equivalent to styrene, suggesting that the reactivity is mainly determined by the chemical reactivity of the ended double bond.

Web of Science ® 被引用回数 : 12

リンク情報
DOI
https://doi.org/10.1163/1568555042474158
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000226172300010&DestApp=WOS_CPL

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