Feb, 2013
influence of the primary structure of the main chain on backbone stiffness of cylindrical rod brushes
POLYMER JOURNAL
- ,
- ,
- ,
- ,
- ,
- Volume
- 45
- Number
- 2
- First page
- 193
- Last page
- 201
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1038/pj.2012.117
- Publisher
- NATURE PUBLISHING GROUP
The dimensional properties of rod brushes consisting of a flexible polymethacrylate main chain and poly(n-hexyl isocyanate; PHIC) rod side chains have been studied using static light and small-angle X-ray scattering (SAXS) techniques in tetrahydrofuran (THF) at 25 degrees C. The results are compared with those consisting of a flexible polystyrene main chain and PHIC side chains (VB-HIC-N-s-H, where N-s is the weight-averaged degree of polymerization of HIC). The rod brushes were prepared through the radical homopolymerizations of alpha-methacryloyloxyethoxy-omega-acetyl-PHIC macromonomer (MA-HIC-61-Ac) in n-hexane at 60 degrees C. The molecular weight dependence of the z-averaged mean-square radius of gyration (< R-g(2)>(z)) of the brush is quantitatively described in terms of the wormlike cylinder model taking into account the end effects. The main chain stiffness parameter (lambda(-1)(M)) is determined to be 197 nm for poly(MA-HIC-61-Ac), which is approximately three times greater than that for poly(VB-HIC-62-H), which has a polystyrene main chain and the same rod length. The considerably larger stiffness in the polymethacrylate than in the polystyrene is most likely responsible for the larger effective excluded volume effects produced by the freely rotating spacer between the main chain and side rod. A single rod brush of poly(MA-HIC-61-Ac) on a mica surface is clearly observed using atomic force microscopy to reasonably demonstrate the cylindrical rod brushes. Polymer Journal (2013) 45, 193-201; doi:10.1038/pj.2012.117; published online 20 June 2012
- Link information
- ID information
-
- DOI : 10.1038/pj.2012.117
- ISSN : 0032-3896
- Web of Science ID : WOS:000315239100011