J-GLOBAL         Last updated: Jul 2, 2019 at 02:42
Gifu University
Faculty of Education
(BLANK), PhD Pharmaceutical(Gifu Pharmaceutical University)

Research Areas


Academic & Professional Experience

Associate Professor, Gifu University Faculty of Education, Faculty of Education

Published Papers

Unprecedented uncleophile-promoted 1,7-S- or Se-shift reactions under Pummerer reactions of 4-alkenyl-3-sulphinylpyrroles
Beilstein J. Org. Chem.      Oct 2018   [Refereed]
Nitrile Hydration Using Copper Iodide/Cesium Carbonate/DBU in Nitromethane-Water
J. Kuwabara, Y. Sawada, M. Yoshimatsu
Synlett   29 2061-2065   Aug 2018   [Refereed]
Copper-Mediated Reactions of Nitriles with Nitromethanes: Aza-Henry Reactions and Nitrile Hydrations
J. Kuwabara, Y. Sawada, M. Yoshimatsu
Org. Lett.   20 1130-1133   Apr 2018   [Refereed]
Se- and Te-Containing Acetals
Yoshimatsu Mitsuhiro(Gifu University),MuraiToshiaki(Gifu University)
30 597-637   Jun 2007
A Convenient Praparative Method for New 1,3-Bis(hetaryl)-2- chloropropen-1-ones Using-Alkoxy--chloroalkenyllithium Compounds
Yoshimatsu Mitsuhiro(Gifu University),Itoh Yoshiaki(Gifu University),Sakai Miho(Gifu University)
2006-2014   Mar 2007
Yoshimatsu Mitsuhiro(Gifu University),Sakai Miho(Gifu University),Moriura Eri(Gifu University)
498-507   Feb 2007
1,1-Diorganylseleno, 1-Organylseleno-1-organyltelluro, 1,1-Diorganyl- telluroallenes and further derivatives
Yoshimatsu Mitsuhiro(Gifu University)
24 517-526   Nov 2006
Yoshimatsu Mitsuhiro(Gifu University),Gotoh Kohei(Gifu University),Yamamoto Teruhisa(Gifu University)
54 1611-1615   Oct 2006
1,1-Bis(organoselanyl)alk-1-enes and Derivatives
Yoshimatsu Mitsuhiro(Gifu University)
24 547-558   Oct 2006
Mitsuhiro Yoshimatsu(gifu university),Kawamoto Masayo(Gifu University),Gotoh Kohei(Gifu University)
2884-2887   Nov 2005


Terahisa Yamamoto, Eri Moriura, Arisa Sawa, Mitsuhiro Yoshimatsu
Chemistry Letters   37(10) 1046-1047   Dec 2008
The 1-(organoselanyl)perfluoroalkanols 1, 3, 4, and 10 were successfully prepared and reactions with hexanoyl chlorides to produce the corresponding esters 5, 7, and 8, accompanied by the selenoesters 6 were conducted. The DBU-mediated alkylations...
Akinori Itoh, Miho Sakai, Mitsuhiro Yoshimatsu
European Journal of Organic Chemistry   2006-2014
The 1,3-biaryl and 1,3-bis(hetaryl)propen-1-ones 14a-e, 16, 17a-c, 19, 20a and the corresponding acetals 15a-d, 18a and 21a-d were successfully synthesized by a stepwise process: the reaction of α-chloro-β- ethoxyethenylhthium compounds and aldehy...
Mitsuhiro Yoshimatsu, Masataka Kawahigashi, Eiji Honda, Tadashi Kataoka
J. Chem. Soc. , Perkin Trans. 1   695-700
Diazomethane add to the enyne sulfones 1,3,4,6-11 regio- and stereo-selectively to give the 4-alkynyl-5-phenylsulfonyl-4,5-dihydro-3H-pyrazoles 12-15 and 17-19, which are converted by MeLi into the 4-alkynyl-1H-pyrazoles 24, 25, 16, 26, 28, 30 in ...
M. Yoshimatsu, S. Yamaguchi, Y. Matsubara
Journal of the Chemical Society. Perkin Transactions 1   2560-2565
A new α-cyanoformylation of aldehydes and ketones proceeds in good to high yields using α-lithioacrylonitrile. This novel α-cyanoformylation is successfully applied to the preparation of two kinds of hepta-2,4,6-trienals, bearing a 6-cyano group (...
Mitsuhiro Yoshimatsu, Satoshi Gotoh, Kazunari Ikeda, Motonori Komori
J. Org. Chem.   63(19) 6619-6624
2-(Chalcogeno)-1-ethoxyallylic cations 4A are easily generated from the reactions of 2-(chalcogeno)- 1-ethoxyprop-l-en-3-ols 2a-e or 2-(chalcogeno)prop-2-enal acetals 3a-c and TMSOTf and reacted with various nucleophiles to give the adducts 5a-8a,...

Books etc

Science of Synthesis Knowledge Updates, Houben-Weyl Methods of Molecular Transformations
Thieme   2016   
Science of Synthesis, Houben-Weyl Methods of Molecular Transformations
Georg Thieme Verlag KG   2007   
Jan 2002   
Comprehensive Organic Functional Group Transformations
Pergamon Press   1995   

Conference Activities & Talks

イオウで活性化されたアセチレン化合物の化学―新規ヘテロ環合成法の開発について― [Invited]

Research Grants & Projects

Ministry of Education, Culture, Sports, Science and Technology: Grants-in-Aid for Scientific Research(基盤研究(C))
Project Year: 2002 - 2003    Investigator(s): Mitsuhiro YOSHIMATSU
The author originally prepared some 4-alkoxy-1,3-butadienes bearing 1,2-bis(sulfanyl)-or 1-selanyl-2-sulfanyl groups as starting materials of 4-carbon homologations. Treatment of the phenyl propargyl sulfides or selenides with ethyl magnesium brom...
Ministry of Education, Culture, Sports, Science and Technology: Grants-in-Aid for Scientific Research(基盤研究(C))
Project Year: 2000 - 2001    Investigator(s): Mitsuhiro YOSHIMATSU
We have performed the syntheses of the new hepta-2,4,6-trienals using our original methodology, which was based on the Wittig type olefinations using β-alkoxyalkenyl lithiums. A simple process has been shown as follows. It contains two steps, a fi...
Study on Reaction of α-Selenocarbenium Ions and α-Oxycarbenium Ions from Se,O-Heteroacetals
0028 (Japanese Only)
Project Year: 1991 - 1995
Study on Synthesis of Conjugated Enyne and Enediyne
0024 (Japanese Only)
Project Year: 1995 - 1999
Organic Synthesis Using β-Alkoxy alkenyl Lithium
0023 (Japanese Only)
Project Year: 1994 - 2007


特願JP20090026781(A) 20090206 : New Compound Having Pyrimidin-4(3H)-one Structure and Medicine Containing The Same
T. Miura, K. Onoki, S. Sato, R. Sekimoto, T. Ogiya, M. Yoshimatsu